Catalytic methane combustion was carried out over YSZ, Pd/YSZ and Rh/YSZ between 200 700 °C. Despite similar light-off curves for 450 °C, isotopic exchange experiments using CD4 18O2 revealed different behaviour of both supported catalysts regarding the activation reactant molecules. The use C18O2 gas shown to be more appropriate than evaluate bulk oxygen mobility in YSZ at low temperatures. ga...

MFI type zeolite membranes were synthesized on two types of supporting materials, alumina (α-alumina) and yttria-stabilized zirconia (YSZ) coated alumina. Membranes were prepared by template-free secondary growth method with multiple growth steps in order to minimize intercrystalline gaps. Gas permeation characteristics, thermal and hydrothermal stability for MFI type zeolite membranes were exa...

The change in conductivity of Fe and Ti implanted if-sputtered layers of yttria-stabilized zirconia (YSZ) was studied as a function of the temperature (400-800 °C) and oxygen partial pressure. In an oxidized state and in the temperature range of 400600 ° C, the conductivity of the Fe implanted YSZ film ( 15 keV, 8 × 10 '6 at.cm 2) was dominated by the n-type electronic conductivity of a thin Fe...

This paper reports a micromachined chemical sensor intended for harsh environments such as those near hydrothermal vents at the sea floor. The sensor is intended to measure the pH, dissolved H2 and H2S, and temperature. The device is 12 mm in diameter and 6 mm in effective length, including packaging. A YSZ|HgO|Hg solid electrode is used as a common electrode for measurement of the three chemic...

A method is described for quantitatively analyzing the level of interconnectivity of solid-oxide fuel cell electrode phases. The method was applied to the three-dimensional microstructure of a Ni-Y2O3-stabilized ZrO2 (Ni-YSZ) anode active layer measured by focused ion beam scanning electron microscopy. Each individual contiguous network of Ni, YSZ, and porosity was identified and labeled accord...

Following exposure to ppm-level hydrogen sulfide at elevated temperatures, a section of a solid oxide fuel cell (SOFC) Ni-YSZ anode was examined using a combination of synchrotron-based x-ray nanotomography and x-ray fluorescence techniques. While fluorescence measurements provided elemental identification and coarse spatial mapping, x-ray nanotomography was used to map the detailed 3-D spatial...

The Yttria stabilized Zirconia (YSZ) is a standard electrolyte for solid oxide fuel cells (SOFCs), which are potential candidates for next generation portable and mobile power sources. YSZ electrolyte thin films having a cubic single phase allow reducing the SOFC operating temperature without diminishing the electrochemical power density. Films of 8 mol% Yttria stabilized Zirconia (8YSZ) and fi...

Strain confinement in heterostructured films significantly affects ionic conductivity of the electrolytes for solid oxide fuel cells based on a multi-layered design strategy. Nearly ideal tensile strain can be achieved by a dedicated manipulation of the lattice mismatch between adjacent layers and fine control of the layer thicknesses to minimize the formation of dislocations and thus to achiev...