The separations of alcohols with hydrophilic and hydrophobic parts, and the separation of aromatic mixtures, are extremely important processes in gas and petroleum industries. Choosing an adsorbent for performing this separation is the most important part of the process. Silica gel is used as an adsorbent is various techniques such as pressure swing adsorption (PSA) and gas and liquid chromatog...

Ar/CH4/H2 gas mixtures have been used in an attempt to deposit nanocrystalline (NCD) diamond and ultra-nanocrystalline (UNCD) diamond films using hot filament (HF) chemical vapour deposition (CVD). A detailed composition map has been developed for the type of films deposited in the Ar/CH4/H2 system. It was found that the standard gas mixtures of 1%CH4/Ar (+1–2%H2) that are used successfully to ...

The aqueous mixtures of light gas molecules under low-temperature and high-pressure conditions are candidates to form gas hydrate clathrates. The formation of gas hydrate may lead to various problems and extra charges in natural gas production and processing. The presence of hydrate crystals forming a stable solid phase can potentially block the wells, pipes, and process facilities. To avoid su...

Comprehensive two-dimensional gas chromatography can be viewed as a traditional gas chromatography with a sophisticated "elution-resolved" flame ionization detector (GC/FID) or a detector with separation capability. The concept of multidimensional chromatography can be extended to other detectors that also have separation capability, such as ultraviolet, infrared, and mass spectrometer. Mass sp...

Understanding the composition of complex hydrocarbon mixtures is important for environmental studies in a variety of fields, but many prevalent compounds cannot be confidently identified using traditional gas chromatography/mass spectrometry (GC/MS) techniques. This work uses vacuum-ultraviolet (VUV) ionization to elucidate the structures of a traditionally "unresolved complex mixture" by separ...

We use Monte Carlo simulations to study the adsorption and separation of the natural gas components in IRMOF-1 and Cu-BTC metal-organic frameworks. We computed the adsorption isotherms of pure components, binary, and five-component mixtures analyzing the siting of the molecules in the structure for the different loadings. The bulk compositions studied for the mixtures were 50 : 50 and 90 : 10 f...

BACKGROUND The property values of therapeutic gas mixtures are important in designing devices, defining delivery parameters, and in understanding the therapeutic effects. In the medical related literature the vast majority of articles related to gas mixtures report property values only for the pure substances or estimates based on concentration weighted averages. However, if the molecular size ...