NiII and MnIII Schiff base complexes (Salophen-Ni Salophen-MnCl) bearing a pending carboxylic group were prepared characterized. Both grafted onto mesoporous amino-functionalized SBA-15 silica, by formation of an amide function between the propylamine groups support acid functions salophen ligand (corresponding respective to 1.30 wt.% Ni 1.06 Mn). The co-catalytic behaviour free was then evalua...

2-Carboxyphenylacetate (cpa2?) and 1,2-phenylenediacetate (1,2-pda2?) have been reacted with uranyl cations under solvo-hydrothermal conditions to generate six homo- or heterometallic complexes. Both [UO2(cpa)] (1) [UO2(cpa)(phen)] (2), where phen is 1,10-phenanthroline, crystallize as monoperiodic coordination polymers. [Ni(bipy)3][(UO2)2(cpa)3]?2.5H2O (3), a diperiodic network the hcb topolog...

The reaction of one equivalent of [n-Bu4N]2[Ni(opboR2)] with two equivalents of [Cu(pmdta)(X)2] afforded the heterotrinuclear CuIINiIICuII containing bis(oxamidato) type complexes [Cu2Ni(opboR2)(pmdta)2]X2 (R = Me, X = NO3- (1); R = Et, X = ClO4- (2); R = n-Pr, X = NO3- (3); opboR2 = o-phenylenebis(NR-substituted oxamidato); pmdta = N,N,N',N",N"-pentamethyldiethylenetriamine). The identities of...

In the title NiII complex, [Ni(C10H11O2)2(C6H6N2O)2(H2O)2]·2H2O, the divalent Ni ion occupies a crystallographically imposed centre of symmetry and is coordinated by two O atoms from the carboxyl-ate groups of two 2,4,6-tri-methyl-benzoate (TMB) ligands [Ni-O = 2.0438 (12) Å], two N atoms from the pyridyl groups of two isonicotinamide (INA) ligands [Ni-N = 2.1506 (15) Å] and two water mol-ecule...

We describe a series of air-stable NiIII complexes supported by simple, robust naphthyridine-based ligand. Access to the high-valent oxidation state is enabled CF3 ligands on nickel, while naphthyridine exhibits either monodentate or bidentate coordination mode that depends and sterics, enables facile aerobic NiII NiIII. These act as efficient catalysts for photoinduced C(sp2)−H bond trifluorom...

Four new NiII, CoII, ZnII, and CuII complexes with the promising anti-tuberculosis drug (E/Z)-N′-((5-Hydroxy-3,4-bis(hydroxymethyl)-6-methylpyridin-2-yl)methylene)-isonicotino-hydrazide (LH) were synthesized characterized by structural methods: single-crystal X-ray diffraction, vibrational spectroscopy, mass spectrometry. The ZnII metal ions form only amorphous phases various morphologies accor...