crosslinked poly(acrylic acid)s were prepared using two types of crosslinker by precipitation polymerization method in a binary organic solvent. n,n’-methylenebisacrylamide (mba) and polyethylene glycol dimethacrylate (pegdma-330) were used as low-molecular weight and long-chain crosslinkers, respectively. the effect of various types of crosslinkers on polymer characteristics (i.e., gel content...

Introduction The discovery of the conductive properties of conjugated organic polymers in the late 1970s initiated intense investigations of their synthesis, chemistry and physical properties. Today, they are widely studied for various applications, e.g. optoelectronics in displays or organic solar cells. Beyond academic interest in the generation and properties of unusual nanostructures, nanop...

In recent years, advanced nanocomposite materials have been widely used in a large number of commercially valuable industrial applications such as in automobile, marine coatings, aerospace, and construction industries. The nanocomposites are made up of organic polymers and inorganic nanomaterials using different processing techniques. For example, metal, metal oxide, and carbon-based nanomateri...

Organic-based flexible dielectric films with high permittivity (e) are desirable for future applications of organic thin-film transistors, such as smartcards and radio frequency identification (RFID) tags, that concurrently desire flexible or conformable substrates. Advances in the development of all-polymer field-effect transistors (PFETs) have been particularly significant for their potential...

Multidimensional solid-state NMR spectroscopy is used to refine the identification and abundance determination of functional groups in insoluble organic matter (IOM) isolated from a carbonaceous chondrite (Murchison, CM2). It is shown that IOM is composed primarily of highly substituted single ring aromatics, substituted furan/pyran moieties, highly branched oxygenated aliphatics, and carbonyl ...

Conjugated polymers (CPs) are an important class of organic semiconductors that combine novel optoelectronic properties with simple processing from organic solvents. It is important to study CP conformation in solution to understand the physics of these materials and because it affects the properties of solution-processed films. Single-molecule techniques are unique in their ability to extract ...


 Improving Hybrid Solar Cells: Overcoming Charge Extraction Issues in Bulk Mixtures of Polythiophenes and Zinc Oxide Nanostructures! ! Grant Olson! ! ! Organic photovoltaics (OPVs) have received a great deal of focus in recent years as a possible alternative to expensive silicon based solar technology. Current challenges for organic photovoltaics are centered around improving their lifetimes a...

We demonstrate an integration of polymer light-emitting diode ~LED! and polymer transistor in which no patterning of the organic layers is needed. Intrinsic high-mobility semiconducting conjugated polymer poly~3-hexylthiophene!~P3HT! is used as the hole-transport layer for polymer LED. The light emission efficiency is only slightly lower than the LED with conventional heavily doped hole-transpo...

Aligned macroporous monoliths of an organic cage, a polymer of intrinsic microporosity (PIM-1), and a metal-organic framework (HKUST-1) are prepared by a controlled freezing approach. In addition to macropores, all the monoliths contain the intrinsic micropores.

Metal-free organic phosphorescent materials are attractive alternatives to the predominantly used organometallic phosphors but are generally dimmer and are relatively rare, as, without heavy-metal atoms, spin-orbit coupling is less efficient and phosphorescence usually cannot compete with radiationless relaxation processes. Here we present a general design rule and a method to effectively reduc...