1,2-Annulated pyrrolo[2,1,5-de]quinolizin-5-ones (cycl[3.3.2]azin-5-ones) 6a-6k, 8a-8b and 9 have been synthesized by one pot tandem reactions of 2-acetyl-N-phenacylpyridinium bromides (1a-1d) with electron-deficient cyclic alkenes (N-alkyl(aryl)maleimides, benzoquinones and naphthoquinone) in the presence of sodium carbonate as a base and tetrakispyridinecobalt(II) dichromate (TPCD) as an oxid...

The synthesis and tautomeric nature of three xanthene-based bisMETAMORPhos ligands (La-Lc) is reported. Coordination of these bis(sulfonamidophosphines) to Ir(acac)(cod) initially leads to the formation of IrI(LH) species (1a), which convert via formal oxidative addition of the ligand to IrIII(L) monohydride complexes 2a-c. The rate for this step strongly depends on the ligand employed. IrIII c...

The catalytic performance of Fe-Cr/ZrO2 catalysts, prepared by two different methodsscoprecipitation and coprecipitation-impregnation were examined in oxidative dehydrogenation of ethane to ethylene using CO2 as an oxidant. Thermogravimetric analysis and physicochemical characterization such as XPS, XRD, and BET were performed to explore the correlation of catalytic performance with physicochem...

Methane was directly converted to butene liquid fuel by microwave-induced non-oxidative catalytic dehydrogenation under 0.1-0.2 MPa. The results show that, under microwave heating in a two-stage fixed-bed reactor, in which nickel powder and NiO x -MoOy/SiO2 are used as the catalyst, the methane-hydrogen mixture is used as the raw material, with no acetylene detected. The methane conversion is m...

The OH groups on the Zr-based nodes of ultrastable UiO-66 can be metallated with V ions in a facile fashion to give the derivative VUiO-66. This metallated MOF exhibits high stability over a broad temperature range and displays high selectivity for benzene under low-conversion conditions in the vapor-phase oxidative dehydrogenation of cyclohexene (activation energy ∼110 kJ/mol). The integrity o...

Nanocarbons (graphite, tube, diamond) were used as highly efficient catalyst for styrene synthesis from oxidative dehydrogenation of ethylbenzene. Long-time stability and outstanding performance suggested a much more promising future for industrialization of nanocarbon. Metal-free nanocarbons are not highly active for NH3 decomposition while residual metal nanoparticles in commercial CNTs could...

Multi-walled carbon nanotubes (MWCNTs) have been used in the oxidative dehydrogenation of 9,10-dihydroanthracene in an organic solvent (toluene) using molecular oxygen as the oxidant, and in the absence of trace amounts of metals. The process is very selective and almost no anthraquinone is formed. Thermal treatment of the MWCNTs at 2600 °C favors deoxygenation of the support and markedly impro...

Supported vanadium oxides (VOx) are alternative candidates for non-oxidative propane dehydrogenation (PDH) owing to their competitive performance. This paper describes the roles of V−O sites on PDH over monomeric VOx species supported ZrO2, Al2O3 and SiO2. With control pre-reduction, stable structures obtained PDH, including V−O-support (V−O−S), V−OH V=O sites. By tuning V densities individual ...

Carbon nanofibers have been immobilized onto carbon felt as the first step for their industrial application in Oxidative DeHydrogenation (ODH) reactions, exhibiting a stable performance with a high selectivity to styrene in the ODH of ethyl benzene at temperatures around 300 K lower than the actual industrial process, and inhibiting the problem that loose small particle as CNFs shows for being ...

A packed-bed membrane reactor in a distributor configuration is studied theoretically for the oxidative propane dehydrogenation and compared with fixed-bed reactor. Based on detailed 2D models considering two different heat mass transport scale-up including various reactor-to-particle diameter ratios (D/dP) analyzed respect to performance, transfer hot spot formation. Higher selectivities at lo...