The composition shifts of multicomponent mixtures used in low temperature Joule-Thomson refrigerators due to the different solubility in lubricant oils are studied in this paper. A compound of squalane with a high-boiling point temperature is treated as a kind of mineral oil. The Peng-Robinson (PR) equation of state (EOS) is selected to predict the solubilities, in which a group contribution mo...

A new apparatus for the study of vapor-liquid or vapor-liquid-liquid equilibrium has been assembled. The apparatus, based on a static and analytical method, can perform measurements at temperatures from 185 to 320 K and pressures up to 8 MPa. The equilibrium vapor pressures of (xenon + methane) binary mixtures have been measured at seven temperatures, from 189.78 to 273.18 K, and at pressures u...

A composition stream from reservoir to the market has been obtained as a result of upstream, midstream and downstream retrograde gas-condensate models integration. Applications are composition, Peng-Robinson EOS has been chosen as a fluid package. Different production scenarios were observed to define development strategy for rich gas condensate production. VGD and C/V gas drive mechanisms have...

Phase equilibrium calculations for fluids confined inside capillary tubes or porous media are formulated using the isofugacity equations. In this situation, the phase pressures are not equal and it is assumed that they are related by the Laplace equation. With this formulation, existing procedures for phase equilibrium calculations can be readily modified to include capillary effects. In this p...

In this work is examined whether it is possible to predict solid-liquid-vapor phase equilibrium of ternary systems used in the SAS processing by the Peng-Robinson equation of state coupled with the LCVM mixing rules and the UNIFAC method for excess Gibbs free energy calculation. The enthalpy of fusion and the melting point temperature are estimated by group contribution methods. The results sho...

Abstract: A thermodynamic consistency test developed for high pressure binary vapor-liquid mixtures is applied to mixtures containing a supercritical solvent and an ionic liquid. Several authors have reported vapor-liquid equilibrium data on the binary systems supercritical CO2 + 1-butyl-3-methyl imidazolium hexafluorophosphate {[bmim][PF6]}, supercritical CO2 + 1-butyl-3-methyl imidazolium nit...

Cubic equations of state combined with excess Gibbs energy predictive models (like UNIFAC) and equations of state based on applied statistical mechanics are among the main alternatives for phase equilibria prediction involving polar substances in wide temperature and pressure ranges. In this work, the predictive performances of the PC-SAFT with association contribution and Peng-Robinson (PR) co...

The article is devoted to the analysis of flame anchoring mechanism in test case MASCOTTE C-60 RCM2 on supercritical hydrogen/oxygen combustion at 60 bar, with transcritical (liquid) injection oxygen. simulated by means in-house parallel code HeaRT three-dimensional LES framework. cubic Peng–Robinson equation state its improved translated volume formulation assumed. Diffusive mechanisms and tra...

This report summarizes our recent implementation of a crossover formulation in the lattice Boltzmann method and its application modeling transcritical CO2 sequestration water-saturated porous media. A enhancement Peng-Robinson equation state increases accuracy predicting fluid properties conditions, which is relevant sequestration. The leads to prediction liquid-vapor coexistence curves closer ...

A large eddy simulation (LES) and combustion instability analysis are performed using OpenFOAM for the multiple shear-coaxial injector combustor DLR-BKD (in German Deutsches Zentrum für Luft–Brennkammer D, Aerospace Center–Combustion Chamber D), which is a laboratory-scale operating in real-gas environment. The Redlich–Kwong–Peng–Robinson equation of state steady-laminar flamelet model adopted ...