H photocatalysis is of broad interest in materials chemistry and materials science, particularly with the rapid growth of research attention being directed toward energy-related applications, pollution mitigation, and other related areas of environmental impact. A literature survey reveals more than 9000 papers with the word photocatalyst or photocatalysis in the title published during the last...

The semiconductor properties important in the design of photocatalysts required for a photosynthetic system, e.g., a photoelectrochemical cell to split water to hydrogen and oxygen, have largely been taken to be the band gap energy, Eg, and the band-edge locations, Ec and Ev (usually with considerations of factors affecting stability). These affect the amount of solar energy absorbed in the mat...

In this study, the photocatalytic method was used for treating the spent caustic in the wastewater of Olefin units used in petrochemical industries which contain large amounts of total dissolved solids (TDS). By using the synthetic photocatalyst of suspended titanium dioxide and measuring the chemical oxygen demand (COD) which was reduced in the photocatalyst (lbc) process, the values of COD we...

This study presents the development of a novel solid state photocatalyst for the photoinduced controlled radical polymerization of methacrylates under mild UV irradiation (λmax ≈ 365 nm) in the absence of conventional photoinitiators, metal-catalysts or dye sensitizers. The photocatalyst design was based on our previous finding that organic amines can act in a synergistic photochemical reaction...

Since the discovery of the Honda-Fujishima effect of water splitting[1] using a titanium dioxide (TiO2) electrode in the early 1970s, numerous studies have been conducted and are still growing on photocatalytic reactions of TiO2. Titanium dioxide serves as a model case for the mechanistic studies of photocatalysis, but it has a serious drawback as a photocatalyst for water splitting: the band g...

The oxidizing ability of organic dyes is enhanced significantly by photoexcitation. Radical cations of weak electron donors can be produced by electron transfer from the donors to the excited states of organic dyes. The radical cations thus produced undergo bond formation reactions with various nucleophiles. For example, the direct oxygenation of benzene to phenol was made possible under visibl...

High-valent metal-oxo complexes are produced by reductive activation of dioxygen via reduction of metal complexes with reductants and dioxygen. Photoinduced electron transfer from substrates to metal complexes with dioxygen also leads to the generation of high-valent metal-oxo complexes that can oxygenate substrates. In such a case metal complexes act as a photocatalyst to oxygenate substrates ...

Application of titanium dioxide (TiO2) as a photocatalyst has presented a promising avenue for the safe photocatalytic degradation of pollutants. Increasing levels of the release of pharmaceuticals in the environment and formation of the intermediates during their degradation may impose health and environmental risks and therefore require more attention. Photocatalytic degradation of acetylsali...

The combination of TiO₂ photocatalyst and magnetic oxide nanoparticles enhances the separation and recoverable properties of nanosized TiO₂ photocatalyst. Metal-modified (Me = Pd, Au, Pt, Cu) TiO₂/SiO₂@Fe₃O₄ nanocomposites were prepared by an ultrasonic-assisted sol-gel method. All prepared samples were characterized by X-ray powder diffraction (XRD) analysis, Brunauer-Emmett-Teller (BET) metho...

Deposition of titanium dioxide (TiO(2)) on activated carbon (AC) surface has been widely utilized for the production of TiO(2)/AC photocatalyst, which can be used in photo-degradation of pollutants. In this work, a fast and simple digestion procedure has been developed for the spectrophotometric quantitative analysis of TiO(2) in TiO(2)/AC photocatalyst. Microwave-assisted digestion was used in...