نتایج جستجو برای: photochemical oxidation

تعداد نتایج: 126898  

2007
E. J. K. Nilsson M. S. Johnson F. Taketani Y. Matsumi M. D. Hurley T. J. Wallington

The formation of formaldehyde via hydrogen atom transfer from the methoxy radical to molecular oxygen is a key step in the atmospheric photochemical oxidation of methane, and in the propagation of deuterium from methane to molecular hydrogen. We report the results of the first investigation of the branching ratio for HCHO and HCDO formation in the CH2DO + O2 reaction. Labeled methoxy radicals (...

Journal: :Atmospheric Chemistry and Physics 2021

Abstract. Atmospheric chromophoric organic matter (COM) plays a fundamental role in photochemistry and aerosol aging. However, the effects of photodegradation on chemical components photochemical reactivity COM remain unresolved. Here, we report potential carbon contents, optical properties, fluorophore aerosol. After 7 d photodegradation, fluorescent intensity absorption coefficient decrease b...

Journal: :Zeitschrift fur Naturforschung. Teil B, Chemie, Biochemie, Biophysik, Biologie und verwandte Gebiete 1967
G Tomita

The heat, ultraviolet and rihoflavin-sensitized visible inactivations of taka-amylase A are strongly inhibited by the presence of its substrate. The stabilization of the secondary structure of enzyme protein by the conformation change due to the formation of enzyme-substrate and -product complexes is responsible for the protection of enzyme from the heat inactivation. The photoinactivations are...

2006
A. R. Garcia R. Volkamer L. T. Molina M. J. Molina J. Samuelson J. Mellqvist B. Galle S. C. Herndon C. E. Kolb

Photochemical pollution control strategies require an understanding of photochemical oxidation precursors, making it important to distinguish between primary and secondary sources of HCHO. Estimates for the relative strengths of primary and secondary sources of formaldehyde (HCHO) were obtained using a statistical regression analysis with time series data of carbon monoxide (CO) and glyoxal (CH...

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