We tested the hypothesis that the level of protein adsorption onto polyelectrolyte multilayers (PEMs) is influenced by the chain stiffness of the polymers forming the multilayer. The implication being that by altering the chain stiffness, PEMs can be formed that promote or inhibit protein adsorption. Protein adsorption to PEMs consisting of flexible and semi-flexible polyelectrolytes was invest...

Polyelectrolyte surface-modified cowpea mosaic virus (CPMV) can be used for the templated synthesis of narrowly dispersed gold nanoparticles. Cationic polyelectrolyte, poly(allylamine) hydrochloride, is electrostatically bound to the external surface of the virus capsid. The polyelectrolyte-coated CPMV promotes adsorption of aqueous gold hydroxide anionic species, prepared from gold(III) chlori...

CsgD and cyclic-3',5'-di-guanylate are key regulators of biofilm formation in Salmonella enterica serovar Typhimurium. Our results show that polynucleotide phosphorylase and NlpI oppositely altered expression of CsgD. Polynucleotide phosphorylase and NlpI also had opposite effects on the expression of yjcC, which codes for a cyclic-3',5'-di-guanylate phosphodiesterase affecting CsgD expression.

The gene for the enzyme guanosine pentaphosphate synthetase I (GPSI) from Streptomyces antibioticus has been cloned and sequenced. The cloned gene functioned as a template in the streptomycete coupled transcription-translation system and directed the synthesis of a protein with the properties expected for GPSI. Sequencing of the cloned gene identified an open reading frame of 740 amino acids wh...

We study the effect of electrostatic interactions on the distribution function of the end-to-end distance of a single polyelectrolyte chain in the rod-like limit. The extent to which the radial distribution function of a polyelectrolyte is reproduced by that of a wormlike chain with an adjusted effective persistence length is investigated. Strong evidence is found for a universal scaling formul...

     Among the numerous nanosized drug delivery systems currently under investigation, carbon nanotubes (CNTs), regardless of being single or multiple-walled, offer several advantages and are considered as promising candidates for drug targeting. Despite the valuable potentials of CNTs in drug delivery, their toxicity still remains an important issue. After the PEGylation of single-walled CNTs ...

Quasi-elastic light scattering (QELS), electrophoretic light scattering (ELS), CD spectroscopy, and azide binding titrations were used to study the complexation at pH 6.8 between ferrihemoglobin and three polyelectrolytes that varied in charge density and sign. Both QELS and ELS show that the structure of the soluble complex formed between ferrihemoglobin and poly(diallyldimethylammonium chlori...

cupper oxide structures with a variety of novel morphologies are synthesized using cupper foil as substrate via a solution route. the structure, morphology and phase of the as-synthesized nanostructures are analyzed by various techniques. sem images show gradual development of hierarchical structures of copper oxide with different morphology. in order to study the effect of reaction time and te...

in this pepper fe2o3 nanoparticles were synthesized via a fast microwave method. then fe2o3-tio2 nanocomposites were synthesized by a sonochemical-assisted method. the prepared products were characterized by x-ray diffraction pattern, scanning electron microscopy and fourier transform infrared spectroscopy. the photocatalytic behaviour of fe2o3-tio2 nanocomposites was evaluated using the degrad...

Xylan is known as a strength-enhancing agent for paper. However, it is difficult to adsorb xylan onto cellulose fibers because it carries the same negative charge as fibers. Therefore, either cationization of xylan or addition of cationic polyelectrolyte is required to maximize the effect of xylan use. In this study, cationic polyelectrolyte was used to promote xylan adsorption onto cellulose f...