نتایج جستجو برای: quenching effect

تعداد نتایج: 1653404  

1999
T. S. Jensen V. E. Markushin

We have calculated differential, total and transport cross sections for muonic hydrogen in the n = 2 state scattering from hydrogen. The metastable fraction of the 2S state that slows down below the 2P threshold without undergoing collisional quenching has been calculated as a function of the initial kinetic energy using a Monte Carlo kinetics program. Contrary to earlier estimates, the metasta...

Journal: :Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 2014
Jun Fan Ruiping Li Pingping Xu Junwei Di Yifeng Tu Jilin Yan

In this work, we synthesized a trypsin-stabilized fluorescent gold nanocluster. It was found that sulfide interacted with the nanocluster, which could result in significant fluorescence quenching. With this quenching effect, a fluorescence sulfide sensor was developed. This sensor responded linearly to sulfide in the range of 50 nM to 8 μM, and was capable of detecting sulfide as low as 5.5 nM....

Journal: :The journal of physical chemistry. B 2010
Pen-Nan Liao Christoph-Peter Holleboom Laura Wilk Werner Kühlbrandt Peter J Walla

Recently, excitonic carotenoid-chlorophyll interactions have been proposed as a simple but effective model for the down-regulation of photosynthesis in plants. The model was proposed on the basis of quenching-correlated electronic carotenoid-chlorophyll interactions (Car S(1) → Chl) determined by Car S(1) two-photon excitation and red-shifted absorption bands. However, if excitonic interactions...

Journal: :Water research 2014
Elfrida M Carstea Andy Baker Magdalena Bieroza Darren M Reynolds John Bridgeman

The fluorescence intensity of dissolved organic matter (DOM) in aqueous samples is known to be highly influenced by temperature. Although several studies have demonstrated the effect of thermal quenching on the fluorescence of DOM, no research has been undertaken to assess the effects of temperature by combining fluorescence excitation - emission matrices (EEM) and parallel factor analysis (PAR...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه تحصیلات تکمیلی علوم پایه زنجان - دانشکده شیمی 1391

in this thesis a calibration transfer method is used to achieve bilinearity for augmented first order kinetic data. first, the proposed method is investigated using simulated data and next the concept is applied to experimental data. the experimental data consists of spectroscopic monitoring of the first order degradation reaction of carbaryl. this component is used for control of pests in frui...

2012
Maria Olejnik Łukasz Bujak Sebastian Mackowski

We demonstrate strong spectral dependence of the efficiency of fluorescence quenching in molecular systems composed of organic dyes and gold nanoparticles. In order to probe the coupling with metallic nanoparticles we use dyes with varied spectral overlap between the plasmon resonance and their absorption. Hybrid molecular structures were obtained via conjugation of metallic nanoparticles with ...

Journal: :Faraday discussions 2012
C Patrick Royall Alex Malins

Interactions between colloidal particles have hitherto usually been fixed by the suspension composition. Recent experimental developments now enable the control of interactions in situ. Here we use Brownian dynamics simulations to investigate the effect of controlling interactions upon gelation, by "quenching" the system from an equilibrium fluid to a gel. We find that, contrary to the normal c...

Journal: :The journal of physical chemistry. A 2005
Claudia G Martínez Steffen Jockusch Marco Ruzzi Elena Sartori Alberto Moscatelli Nicholas J Turro Anatoly L Buchachenko

An absorptive chemically induced dynamic electron polarization (CIDEP) was generated by the quenching of singlet oxygen by nitroxide radicals (TEMPO derivatives). The spin polarization decay time of the nitroxide (measured by time-resolved EPR) correlates with the lifetime of singlet oxygen (measured by singlet oxygen phosphorescence spectroscopy). In addition, a deuterium isotope effect on the...

Journal: :iranian journal of basic medical sciences 0
jamshid l manzoori department of analytical chemistry, faculty of chemistry, university of tabriz, tabriz, iran mohammad amjadi tuberculosis and lung disease research center and faculty of pharmacy, tabriz university of medical sciences, tabriz, iran naser soltani tuberculosis and lung disease research center and faculty of pharmacy, tabriz university of medical sciences, tabriz, iran abolghasem jouyban drug applied research center and faculty of pharmacy, tabriz university of medical sciences, tabriz, iran

objective(s):cefixime (cfx), is a semi-synthetic third-generation oral cephalosporin antibiotic that is prescribed for the treatment of susceptible infections. there are some procedures for the determination of cfx in pharmaceutical formulations and biological samples. herein a spectrofluorimetric method was proposed for cfx determination based on the fluorescence quenching of terbium-danofloxa...

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