X-ray fluorescence spectroscopy is a widely used method for determining the electronic configuration and local structure of dilute species with high sensitivity. In the dilute limit, and for thin films, the X-ray fluorescence signal is directly proportional to the atomic sub-shell absorption coefficient. However, for concentrated samples, the well-documented self-absorption effect often leads t...

The group of 2D materials contains almost all the elements of the periodic table. In contrast to the graphene sheet, they are abundant, this creates a variety of electronic properties including metals, semimetals, insulators and semiconductors. Band gaps of these materials are direct or indirect by ranging from ultraviolet to infrared, for this reason, have received much attention for nanoelect...

Fluorescence tomographic reconstruction, based on the detection of photons coming from fluorescent emission, can be used for revealing the internal elemental composition of a sample. On the other hand, conventional X-ray transmission tomography can be used for reconstructing the spatial distribution of the absorption coefficient inside a sample. In this work, we integrate both X-ray fluorescenc...

A convenient rhenium-based multimodal mitochondrial-targeted probe compatible with Synchrotron Radiation X-ray Fluorescence nano-imaging.

This paper reports on several developments of X-ray fluorescence techniques for macromolecular crystallography recently implemented at the National Institute of General Medical Sciences and National Cancer Institute beamlines at the Advanced Photon Source. These include (i) three-band on-the-fly energy scanning around absorption edges with adaptive positioning of the fine-step band calculated f...

The energy dispersive X-ray fluorescence analysis (ED-XRFA) is a well-established tool for multielement composition analysis in different fields/1/. It works non-conducting and it is non-destructive. No particular sample preparation is necessary if the specimens have an almost planar and smooth surface. For the characterization of precious gemstone material it is also important that the deposit...

Measurements of the cosmic-ray air-shower fluorescence at extreme energies require precise knowledge of atmospheric conditions. The absolute calibration of the cosmic-ray energy depends on the absorption of fluorescence light between its origin and point of its detection. To reconstruct basic atmospheric parameters we review a novel analysis method based on twoand multi-angle measurements perfo...

Resonant inelastic x-ray scattering (RIXS) has been observed in many systems above and below their core threshold. Below threshold, inelastic-loss features are observed, which disperse linearly with excitation energy, but as the excitation increases above the core binding energy, in general nonlinear dispersive effects are observed. These two effects are described by the same physics of coheren...