‘Plug-and-play’ simplified electrochemical atom transfer radical polymerisation of PEGA480 under potentiostatic and galvanostatic conditions proceeds with very good control to conversions up 83%.

Abstract Atom-transfer radical polymerization (ATRP) is a well-known technique for controlled polymer synthesis. However, the ATRP usually employed toxic heavy metal ionas as catalyst and was susceptible to molecular oxygen, which made it should be conducted under strictly anoxic condition. Conducting ambient biocompatible conditions major challenge. In this study, cytochrome C explored an effi...