Let D be a digraph with n vertices and arcs. The Laplacian the signless matrices of are, respectively, defined as L(D)=Deg+(D)−A(D) Q(D)=Deg+(D)+A(D), where A(D) represents adjacency matrix Deg+(D) diagonal whose elements are out-degrees in D. We derive combinatorial representation regarding first few coefficients (signless) characteristic polynomial provide concrete directed motifs to highligh...