نتایج جستجو برای: sime
تعداد نتایج: 230 فیلتر نتایج به سال:
Features Bridging the Gap: Delivering Distance Education Courses on the Web —Peter Golz 17 Computer Assisted Writing in CALL—Chiaki Iwai 25 Creating Web-Based Soap Operas for Learning English—Ken Koebke 35 Multimedia in Language Instruction: Challenges and Solutions —Jörg Roche 45 Teaching the Previous fin de stiele w i t h the Help of Current fin de siMe Technology—Gary Smith 53 Accessible Aut...
In this paper, we employ fuzzified Simulated Evolution (SimE) algorithm for combinational digital logic design targeting area, delay and power as objectives. This technique is considered to be an evolutionary technique in logic design compared to conventional technique which uses deterministic algorithms for logic design. The performance of the proposed algorithm is evaluated using selected ISC...
Fifteen C-diazaborolyl-ortho-carboranes, 1-R'-2-R''-1,2-C(2)B(10)H(10), where R' represents the groups 2-(1,3-Et(2)-1,3,2-N(2)BC(6)H(4))-, 2-(1,3-Ph(2)-1,3,2-N(2)BC(6)H(4))-, 2-(1,3-Ph(2)-5,6-Me(2)-1,3,2-N(2)BC(6)H(2))-, 2-(1,3-(i)Pr(2)-1,3,2-N(2)BC(6)H(4))-, and 2-(1,3,2-N(2)BC(6)H(6))- and where R'' is H, Me, Ph, (t)Bu or SiMe(3), were synthesized. Cyclic voltammetry studies of the compounds ...
The ligation of a N-heterocyclic carbene (NHC) to group 11 metal salts (Cu, Ag) was explored as an alternative to PR(3) ligands for the formation of copper- and silver-chalcogenolate cluster complexes. AgOAc and CuCl salts ligate with the NHC 1,3-di-isopropylbenzimidazole-2-ylidene ((i)Pr(2)-bimy) forming [Ag(OAc)((i)Pr(2)-bimy)] 1, [Ag(OAc)((i)Pr(2)-bimy)(2)] 2, [CuCl((i)Pr(2)-bimy)](2)3 and [...
A systematic study of the stoichiometric alkylation reactions of 2,2,2-trifluoroacetophenone 1 with [ZnR(2)(TMEDA)] (R= Me, Et, (t)Bu, CH(2)SiMe(3); TMEDA= N,N,N',N'-tetramethylethylenediamine) monitored by (1)H and (19)F NMR spectroscopy is presented. For R = Me, Et the alkylation products alkyl(alkoxides) [(TMEDA)Zn(R){OC(CF(3))(R)Ph}] (R = Me, 2: Et, 3) are obtained as the single products of...
Cyclometalated aryl tetra- or trichlorido cyclopentadienyl tantalum complexes [TaXCl(3){C(6)H(4)(2-CH(2)NMe(2))-κ(2)C,N}] (X = Cl 1, η(5)-C(5)H(5)2, η(5)-C(5)H(4)(SiMe(3)) 3, η(5)-C(5)Me(5)4) containing a five-membered TaC(3)N chelate ring were synthesized by reaction of the TaXCl(4) (X = Cl, η(5)-C(5)H(5), η(5)-C(5)H(4)(SiMe(3)), η(5)-C(5)Me(5)) with the appropriate lithium aryl reagent [Li{C(...
Abstract Using previously established salt‐metathesis procedures at low temperature, heterobimetallic ate complexes Li 6 Eu II ( n ‐Bu) 8 (thf) and 3 Y III i 4 could be synthesized their solid‐state structures analyzed by X‐ray diffraction. Recently described complex Y( was probed as a precursor in protonolyses with various amines, revealing distinct reaction pathways. Identified products compr...
Molecules containing catenated heavy group 14 atoms are known to exhibit the interesting property of σ-bond electron delocalization. While this is well studied for oligo- and polysilanes the current paper addresses the UV-absorption properties of small tin containing oligosilanes in order to evaluate the effects of Sn-Si and Sn-Sn bonds as well as the results of substituent exchange from methyl...
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