Based on plasma-treated single wall carbon nanotubes (SWCNTs), SWCNT/SiO(2) and thiol groups-functionalized SWCNT/SiO(2) hybrids have been fabricated through a sol-gel process. By means of thiol groups, Ag nanoparticles have been in situ synthesized and bonded onto the SiO(2) shell of SWCNT/SiO(2) in the absence of external reducing agent, resulting in the stable carbon nanotube/SiO(2)/Ag nanop...

The adsorption of simple benzene derivatives composed of a benzene ring with NO2, CH3, or NH2 functional groups on a semiconducting single-wall carbon nanotube is studied using the density-functional theory within the local-density approximation. The effects of molecular relaxation in the adsorption process are obtained, as well as the adsorption energies and equilibrium distances for several m...

In this work, the structural and electronic properties of folic acid molecule on functionalized (7,0)zigzag single-walled carbon nanotube was studied in gas phase on the basis of density functionaltheory (DFT). Furthermore, covalent interaction of folic acid with single-walled carbon nanotube wasinvestigated and its quantum molecular descriptors and binding energies were calculated. The DFTB3LY...

Carboxylic functionalization (-COOH groups) of carbon nanotubes is known to improve their dispersion properties and increase the electrical conductivity of carbon-nanotube-polymer nanocomposites. We have studied experimentally the effects of this type of functionalization on the thermal conductivity of the nanocomposites. It was found that while even small quantities of carbon nanotubes (~1 wt ...

In this paper we report, for the first time, the alignment enhanced photoconductivity of single wall carbon nanotube films upon laser illumination. The photoconductivity exhibited an increase, decrease or even 'negative' values when the laser spot was on different positions between contact electrodes, showing a 'position' dependent photoconductivity of partially aligned films of carbon nanotube...

An in situ composite synthesis technique has been developed by grafting polystyrene chains onto single-wall carbon nanotubes (SWNTs) via a single-step debundling/polymerization scheme. The method, based on established anionic polymerization techniques, eliminates the need for nanotube pretreatment prior to functionalization and allows attachment of polymer molecules to pristine tubes without al...

The fundamental relations governing the geometry of carbon nanotubes are reviewed, and explicit examples are presented. A framework is given for the symmetry properties of carbon nanotubes for both symmorphic and non-symmorphic tubules which have screw-axis symmetry. The implications of symmetry on the vibrational and electronic structure of ID carbon nanotube systems are considered. The corres...

Internal functionalization of single-walled nanotubes is an attractive, yet difficult challenge in nanotube materials chemistry. Here we report single-walled metal oxide nanotubes with covalently bonded primary amine moieties on their inner wall, synthesized through a one-step approach. Conclusive molecular-level structural information on the amine-functionalized nanotubes is obtained through m...

Carbon nanotubes are a new allotrope of carbon which emerged from the fullerene family [1]. Carbon nanotubes have been discovered by high resolution transmission electron microscopy (HRTEM) in 1991 by Iijima [2]. A single wall carbon nanotube is constituted of one atomic plane with a graphite-like arrangement of C atoms – called a graphene sheet – which is perfectly rolled into a cylinder (Fig....