Four contrasting descriptions of the gas-particle partitioning of SOCs are currently used: the Junge-Pankow adsorption model, the empirical Finizio organic matter (OM) absorption relationship, the Harner-Bidleman OM absorption model, and a dual black carbon (BC) adsorption and OM absorption model. Use of these four descriptions in a box model resulted in very different global fates, particularl...

The present work investigates the effect of jet-exit Reynolds number (Re) on soot particle size and flame temperature in n-butane jet flames. Correlation with volume fraction (fv), precursor (polycyclic aromatic hydrocarbons or PAH), reaction zone (OH) is also examined. investigated flames (Re=5000–21,500) are identical as companion (Part 1). was measured a low-sooting region using fine-wire th...

The analysis of soot formation and oxidation is essential for Diesel engine development to meet future pollutant emission reduction requirements. In recent years laser-induced incandescence (LII) has developed to a powerful tool for soot diagnostics in flames, even in the challenging environment of Diesel combustion. This work presents some recent applications of LII for soot particle sizing in...

The flame and soot structure, including soot primary particle nucleation, surface growth and oxidation properties, of 6 premixed and 20 diffusion flames were studied experimentally for various fuels, at temperatures of 1400-2350 K and at pressures of 13-811 kPa (0.1-8.0 atm). Measurements were made along the axes of flames with the reactants at normal temperature (300 K). The following properti...

Black carbon-containing aerosol particles play an important role in the direct and indirect radiative forcing of climate. However, the magnitude and sign of the net radiative effect is strongly dependent on the physical properties of the black carbon (BC) component of the particles, such as mass concentration, number size distribution and mixing state. Here we use a global aerosol model combine...

The growth of hydrocarbon molecules up to sizes of incipient soot is computed in premixed laminar flames using kinetic Monte Carlo and molecular dynamic methodologies (AMPI code). This approach is designed to preserve atomistic scale structure (bonds, bond angles, dihedral angles) as soot precursors evolve into three-dimensional structures. Application of this code to aliphatic (acetylene) and ...

Soot, which is produced from biomass burning and the incomplete combustion of fossil and biomass fuels, has been linked to regional and global climate change and to negative health problems. Scientists measure the properties of soot using a variety of methods in order to quantify source emissions and understand its atmospheric chemistry, reactivity under emission conditions, interaction with so...

Knowledge of the chemical structure of young soot and its precursors is very useful in the understanding of the paths leading to soot particle inception. This paper presents analyses of the chemical functional groups, based on FT-IR and 1H NMR spectroscopy of the products obtained in an ethylene inverse diffusion flame. The trends in the data indicate that the soluble fraction of the soot becom...

Soot is an important material with impacts that depend on particle morphology. Transmission electron microscopy (TEM) represents one of the most direct routes to qualitatively assess characteristics. However, producing quantitative information requires robust image processing tools, which complicated by low contrast and complex aggregated morphologies characteristic soot. The current work prese...