Herein, an NMR spectral analysis was performed of a mixture diastereomeric acetals synthesized from 2-fluorobenzaldehyde and racemic 4-methylpentan-2-ol. The simulated 1H- 13C-NMR spectra individual diastereomers, as well their superimposed summed spectra, were compared with the obtained experimental spectra. Spin simulation proton signals particularly useful for assignment aromatic part molecu...