The lithiation of the NHC ligand backbone in Cp(CO)2Mn(IMes) followed by transmetalation on C4 carbenic position with Cp(CO)2FeI led to heterobimetallic complex Cp(CO)2Mn(?-dIMes)Fe(CO)2Cp bearing anionic ditopic imidazol-2,4-diylidene dIMes ligand. Subsequent treatment later TfOH induced a selective decoordination [Cp(CO)2Mn] fragment form cationic abnormal [Cp(CO)2Fe(aIMes)](OTf), which was f...

The molecular structures, chemical bonding and magnetochemistry of the three-coordinate iron(II) NHC complexes [(NHC)Fe{N(SiMe(3))(2)}(2)] (NHC = IPr, 2; NHC = IMes, 3) are reported.

The main results: A ring R is CN if and only if for any x ∈ N(R) and y ∈ R, ((1+x)y)n+k = (1+x)n+kyn+k, where n is a fixed positive integer and k = 0, 1, 2; (2) Let R be a CN ring and n ≥ 1. If for any x, y ∈ R\N(R), (xy)n+k = xn+kyn+k, where k = 0, 1, 2, then R is commutative; (3) Let R be a ring and n ≥ 1. If for any x ∈ R\N(R) and y ∈ R, (xy)k = xkyk, k = n, n + 1, n + 2, then R is commutati...

In this paper we partially answer two open questions concerning clean rings. First, we demonstrate that if a quasi-continuous module is strongly clean then it is Dedekind-finite. Second, we prove a partial converse. We also prove that all clean decompositions on submodules of continuous modules extend to the entire module.

The syntheses and structures of copper(i) chalcogenone complexes are described. The homoleptic mononuclear copper(i) complexes [(IPr[double bond, length as m-dash]E)2Cu]ClO4, IPr[double bond, length as m-dash]E, 1,3-bis(2,6-diisopropylphenyl)imidazoline-2-thione (1) and 1,3-bis(2,6-diisopropylphenyl)imidazoline-2-selone (2); [(IMes[double bond, length as m-dash]E)2Cu]ClO4, IMes[double bond, len...

In this paper, we investigate self-dual codes over finite rings, specifically the ring Z2m of integers modulo 2m . Type II codes over Z2m are introduced as self-dual codes with Euclidean weights which are a multiple of 2m+1. We describe a relationship between Type II codes and even unimodular lattices. This relationship provides much information on Type II codes. Double circulant Type II codes ...