We have developed a method for evaluating the specific heat of lattice spin systems. It is based on the knowledge of high-temperature series expansions, the total entropy of the system, and the low-temperature expected behavior of the specific heat as well as the ground-state energy. By the choice of an appropriate variable ~entropy as a function of energy!, a stable interpolation scheme betwee...

The thermodynamic functions such as enthalpy (H), Gibbs free energy (G) and entropy (S) ofPyrazole was theoretically studied at 5 different temperatures 25, 30, 35, 40 and 45°C by usingGussian o3, software. First, the structural optimization of isolated Pyrazole was done in the gas phaseby appling the Density Functional Theory (B3LYP) level with 3-21G, 6-31G and 6-31+G(d) basissets. Moreover, v...

In this work, low temperature thermodynamic behaviour in the context of dissipative diamagnetism with anomalous coupling is analyzed. We find that finite dissipation substitutes the zero-coupling result of exponential decay of entropy by a power law behaviour at low temperature. For Ohmic bath, entropy vanishes linearly with temperature, T , in conformity with Nernst’s theorem. It is also shown...

Different equations have been proposed for estimating the glass transition temperature of amorphous mixtures. All such expressions lack a term to account for the effect of the entropy of mixing on the glass transition. An entropy based analysis for the glass transition of amorphous mixtures is presented. The treatment yields an explicit mixing term in the expression for the glass transition tem...

The configurational entropy is among the key observables to characterize experimentally the formation of a glass. Physically, it quantifies the multiplicity of metastable states in which an amorphous material can be found at a given temperature, and its temperature dependence provides a major thermodynamic signature of the glass transition, which is experimentally accessible. Measurements of th...

Elution and solvation processes in liquid chromatography may be controlled by temperature changes. In the case of solvent adsorption, the temperature influences the amount of adsorbed solvent as well as the enthalpy and entropy of the solvation process. In this work, the thermodynamic parameters of organic solvents used as organic modifiers in the reversed-phase high-performance liquid chromato...

Off-stoichiometric alloys based on Ni2MnIn have drawn attention due to the coupled first order magnetic and structural transformations, and the large magnetocaloric entropy associated with the transformations. Here we describe calorimetric and magnetic studies of four compositions. The results provide a direct measure of entropy change contributions at low temperatures as well as at the first-o...

We examine the role of particle nucleation in the initial universe, and argue that there is a small effect due to particle nucleation in terms of lowering initial temperature, in tandem with energy density and scale factor contributiosn. If such scaling exists as a major order effect, then quenching of temperature proportional to a vacuum nucleation at or before the electroweak era is heavily i...

Abstarct: Flow through pipes and heating situations find wide applications in industry. Depending on the fluid properties, temperature field in the pipe changes. This in turn results in thermodynamic irreversibility in the flow system. Thermodynamic irreversibility can be quantified through amount of entropy generation in the thermal system. Consequently, in the present study, the influence of ...

Magnetic field effect on local entropy generation due to steady two-dimensional laminar forced convection flow past a horizontal plate was numerically investigated. This study was focused on the entropy generation characteristics and its dependency on various dimensionless parameters. The effect of various dimensionless parameters, such as Hartmann number (Ha), Eckert number (Ec), Prandtl numbe...