The title compound, [Sn(C6H5)2Cl2(CH4N2S)2], has been obtained from the reaction between Sn(C6H5)2Cl2 and SC(NH2)2. The asymmetric unit consists of one half of the mol-ecular unit, the remainder generated by a twofold rotation axis located along the Cl-Sn-Cl bonds. The Sn(IV) atom is coordinated by two phenyl groups, two Cl atoms and two thio-urea ligands in an all trans octa-hedral C2Cl2S2 env...

Mol-ecules of the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)], lie on a twofold rotation axis which passes through the Sn atom. The Sn(IV) atom exists in a distorted tetra-hedral geometry. Adjacent mol-ecules are linked by weak Sn⋯Cl contacts [3.703 (1) Å], forming a linear chain motif extending along the b axis.

In the title salt, [Sn(CH(3))(2)Cl(CH(4)N(3)S)]Cl, the Sn(IV) atom is five-coordinated in a distorted trigonal-bipyramidal geometry with two methyl groups and one S atom in the equatorial plane, and one N atom and one Cl atom occupying the apical positions. In the crystal, mol-ecules are linked by inter-molecular N-H⋯S hydrogen bonds with set graph-motif C(4) along [010]. N-H⋯ Cl hydrogen bonds...

The title compound, [Sn(C4H9)2(C6H5COO)2], was synthesized in order to study the inter-action between di-n-butyl-tin(IV) oxide and some carb-oxy-lic acids. Di-n-butyl-tin(IV) dibenzoate, nBu2Sn(obz)2, exhibits the same structural features as other diorganotin(IV) dibenzoates characterized by an unsymmetrical bidentate bonding mode [Δ(Sn-O) ≃ 0.4 Å] of the two benzoate groups to tin. In a first ...