One-dimensional titania nanostructures can serve as a support for light absorbing molecules and result in an improvement in the short circuit current (Jsc) and open circuit voltage (Voc) as a nanostructured and high-surface-area material in dye-sensitized solar cells. Here, self-assembled amyloid-like peptide nanofibers were exploited as an organic template for the growth of one-dimensional tit...

Hollow titania nanoparticles of single-nanometer size have been prepared from titanium oxysulfate (TiOSO₄) using poly(amidoamine) (PAMAM) dendrimer molecules (Generations 5 with amino terminal groups) as a template. At low pH (pH 1), hydrolysis of the titania precursor was attenuated and the sol-gel reaction preferentially proceeded at the dendrimer surface. Calcination at 450°C yielded crystal...

Fifteen commercial titania (titanium(IV) oxide; TiO 2) powders were modified with gold by photodeposition to prepare photocatalysts that work under irradiation with light in the visible range (vis). The gold-modified titania (Au/TiO 2) powders were characterized by diffuse reflectance spectroscopy (DRS), field-emission scanning electron microscopy (FE-SEM), scanning transmission microscopy (STE...

One important aid in understanding catalysis by gold nanoparticles would be to understand the strength with which they bond to different support materials and the strength with which they bond adsorbed intermediates, and how these strengths depend on nanoparticle size. We present here new measurements of adsorption energies by single crystal adsorption calorimetry, and new analyses of other rec...

The coating of solid surfaces with inorganic materials is a promising approach not only to impart various functionalities but also to modify physicochemical properties that are affected by the geometry/structure of the coating. In this study, a silica-hexadecyltrimethylammonium (silica-CTA) hybrid layer was deposited on monodispersed spherical particles composed of titania and octadecylamine (t...

A carbon foam using coal tar pitch as precursor was prepared and investigated as support for titanium oxide for the photocatalytic degradation of phenol. The performance of the carbon foam/titania composite was compared to those of unsupported titania and other activated carbon composites from the literature. The photodegradation rate of phenol over the catalysts under UV illumination was fitte...

Memristive behavior is defined as a resistive switching loop which can be observed from the current-voltage (I-V) characteristic of a material. This paper reports the application of TiO2 (titania) nanostructures as an active layer for a memristive device instead of using titania thin film in nanoscale thickness as reported by other researchers. 60 nm thickness of titania thin film was deposited...