Introduction Archaeochemists are called on to analyze a wide variety of samples, ranging from metals, pigments, and glasses to bones, stones, and soils. In most cases these samples are solids. Although non-destructive and/or micro-sample analyses are preferable for these cultural resources, in many cases there is a large amount of material available for analysis. In those instances where non-de...

Bone lead measurements can assess long-term lead dosimetry because the residence time of lead in bone is long. Bone lead measurements thus complement blood and plasma lead measurements, which reflect more short-term exposure. Although the noninvasive, in vivo measurement of lead in bone by X-ray fluorescence (XRF) has been under development since the 1970s, its use is still largely confined to ...

Total reflection X-Ray Fluorescence (TXRF) is a comparatively new technique of material characterization and trace element analysis. It is an advanced variant of Energy Dispersive X-ray Fluorescence (EDXRF) and is based on the principle of total reflection of X-rays when these radiations fall on a flat smooth surface at a grazing angle less than the critical angle of the sample support. The cri...

The application of electrochemical X-ray fluorescence (EC-XRF), for the detection of palladium (Pd) contamination in a range of solutions containing electrochemically active compounds, present in excess and relevant to the pharmaceutical and food industries, is reported. In EC-XRF, EC is used to electrochemically pre-concentrate metal on an electrode under forced convection conditions, whilst X...

this study is aimed to identify sources of particulate matter with mean aerodynamic diameterbelow 10 μm (pm10) present in the atmosphere of the metropolitan area of mexico city (mamc), usingsamples obtained from january 1st to june 30th, 2009, analyzed with x-ray spectrometric techniques.minivol samplers were used to collect samples on polycarbonate filters in three sites (north, center, andsou...

Polyaminopyridines (PAPy) were chemically prepared from amino-bromopyridines by a CuI/L-proline-catalyzed C-N polycondensation reaction. The formation of the polymer was confirmed by GPC, XRD, XRF, FTIR, UV-vis (λmax = 400 nm), H and C NMR. The number-average molecular weights (Mn) were estimated by end-group analysis using X-ray fluorescence (up to 6000 Da). TGA analysis of PAPy with higher Mn...

Confocal X-ray fluorescence (XRF) spectrometry can be used to perform three-dimensional elemental analysis, which is impossible using general micro XRF without any collimating optics in the detection channel. In this study, we designed, for first time, a new confocal line (C-L-XRF) system that obtain information of larger area and higher intensity analysis than conventional point (C-P-XRF) anal...

Introduction: Giotto (1266–1337) and his workshop realized c. 1315 the large Crucifix now in the Louvre Museum. The conservation of this masterpiece in 2010–2013 in the C2RMF studios gave the opportunity for a comprehensive investigation of the execution technique through a characterization of the paint layers. The first examinations revealed an original gilding and decoration surrounding the C...