Because of its strong pollutant degradation ability, nanoscale zerovalent iron (NZVI) has been introduced to soils and groundwater for remediation purposes, but its impacts on plants are still not very clear. In this work, the effects of low concentration (10-320 μmol/L) NZVI particles on seed germination and growth of peanut plants were evaluated. The exposure of peanut seeds to NZVI at all th...

An innovative full-scale implementation of a permeable reactive barrier, consisting of a double-row of cylinders filled with zerovalent iron shavings, for chromate remediation was monitored over four years. Solid samples were analyzed to elucidate (i) the relevant corrosion mechanisms and products, (ii) the pathways of chromate reduction and immobilization, and (iii) the long-term performance o...

Guar gum can be used to effectively improve stability and mobility of microscale zerovalent iron particles (MZVI) used in groundwater remediation. Guar gum is a food-grade, environment friendly natural polysaccharide, which is often used as thickening agent in a broad range of food, pharmaceutical and industrial applications. Guar gum solutions are non-Newtonian, shear thinning fluids, characte...

This work has investigated the influence of common groundwater anions (Cl , NO3 , SO4 and HCO3 ) on the corrosion behaviour and associated removal of copper (Cu) and zinc (Zn) ions onto nanoscale zerovalent iron particles (nZVI). After 16 week exposure to solutions containing each anion at 10 mM concentrations, nZVI was observed to corrode into different iron (hydr)oxide phases (determined usin...

Common sources of chromium in wastewater are electroplating and leather industries. Hexavalent chromium is more toxic and carcinogenic compared to its trivalent counterpart. Conversion of Cr (VI) to Cr (III) in an aqueous medium both by chemical reduction using zerovalent iron and by photocatalytic reduction using UV radiation and ZnO semiconductor has been investigated using potassium dichroma...

Aided phytostabilization using a combination of compost, zerovalent iron grit and coal fly ash (CZA) amendments and revegetation effectively promoted the biological recovery of mining spoils generated at a gold mine in Portugal. Selective dissolution of spoil samples in combination with solid phase characterization using microbeam X-ray absorption near edge structure (μXANES) spectroscopy and m...

The release of azo dye contaminants from textile industries into the environment is an issue major concern. Nanoscale zerovalent iron (nZVI) has been extensively studied in degradation pollutants such as methyl orange (MO). In this study, was coupled with copper and silver to make trimetallic Fe/Cu/Ag nanoparticles, order enhance MO increase reactivity catalyst by delaying rate oxidation iron. ...