alumina-supported cs3[re(c2o4)3] precursor has been synthesized  for preparation of re-cs/g-al2o3 catalyst. cs3[re(c2o4)3]  has been prepared from the reaction of recl3 with  h2c2o4.2h2o and cscl in water. the complex has been characterized by elemental analysis and various spectroscopy techniques such as ft-ir, uv-vis and 13c-nmr. the complex was supported on γ-al2o3 by column chromatography. ...

Novel uniform single-crystal boehmite leaf-like nanosheets with high anisotropy (with a lateral size of (4.5±0.5 μm)×(9.0±1.0 μm) and a thickness of 60–90 nm) and flower-like superstructures consisting of single-crystal petals were synthesized for the first time by a simple hydrothermal method. After calcination, those boehmite structures can be transformed into single-crystal gamma-alumina nan...

A tomographic heating holder for transmission electron microscopy that can be used to study supported catalysts at temperatures of up to ~1,500°C is described. The specimen is placed in direct thermal contact with a tungsten filament that is oriented perpendicular to the axis of the holder without using a support film, allowing tomographic image acquisition at high specimen tilt angles with min...

High surface area alumina-supported cobalt oxides and carbides were synthesized using a one-pot reverse microemulsion method (followed by carburization for carbides). Two synthesis variations gave fine powders having specific areas ranging from 178−272 m2/g, consisting of oxide or carbide nanoparticles (5−10 nm) dispersed on γ-alumina (10−13 wt% loadings). The resulted materials tested CO2 hydr...

Wettability alteration is one of the most important methods for oil recovery from sandstone and carbonate reservoirs. The effects of salinity, pH, temperature, and chemicals such as surfactants and fatty acids on the alteration of the wettability were described in previous studies. In recent years, attention has been directed to nanoparticles as a wettability alteration agent. The effect of som...

The corrosion phenomenon affects several low carbon steel structures leading to excessive expenditure on coatings and other alternatives. However, the used usually contain compounds that pollute environment. Therefore, environmentally friendly, economical transparent or films have been developed. sol-gel method is a reliable way for development of anticorrosive films, as case alumina silica fil...

Among the various phases of alumina, two phases γ and α are the most widely used in variousindustries. In this paper, γ-Al2O3 porous nanoparticles have been successfully synthesized from a s...

The separation of H2O vapor from (hydrogen-rich) gaseous streams is a topic increasing interest in the context CO2 valorisation, where situ water removal increases product yield and catalyst stability. In this work, composite alumina carbon molecular sieve membranes (Al-CMSM) were prepared phenolic resin solutions loaded with hydrophilic boehmite (γ-AlO(OH)) nanosheets (0.4–1.4 wt. % solution) ...