Minor products in the reaction between substituted 1,3-diiminoisoindolines and 2,5-diamino-3,4-dicyanothiophene were identified as the nickel seco-tribenzoporphyrazines 4 and 5, which have been characterized by UV-vis, MCD, NMR, and mass spectroscopy. Experimentally observed tetraazachlorin-type UV-vis spectra of new seco-tribenzoporphyrazines were explained on the basis of DFT and TDDFT calcul...

Jagiellonian University, Faculty of Chemistr E-mail: [email protected] † Electronic supplementary information ( and UV/Vis absorption spectra of the mon ellipsometric measurements of the photo the thicknesses, UV/Vis absorption spect AFM and XPS measurements of the br brushes in water. Experimental results of the template polymerization. Calculation 10.1039/c4sc04048a Cite this: Chem. S...

A novel class of azo-guanidine compounds is introduced in this article. The novel compound 2-(2-hydroxyphenyl)-1-(phenylamino)-3-(phenylimino)guanidine (AG) was synthesized and well characterized by using different analytical instrumental techniques like elemental analysis, FTIR, (1)H and (13)C NMR, UV-Visible spectroscopy and cyclic voltammetry. The new compound was found interacting with DNA ...

Our computational and experimental investigation of the reaction of anisole with Cl2 in nonpolar CCl4 solution challenges two fundamental tenets of the traditional SEAr (arenium ion) mechanism of aromatic electrophilic substitution. Instead of this direct substitution process, the alternative addition-elimination (AE) pathway is favored energetically. This AE mechanism rationalizes the preferre...

In this paper we demonstrate that the sonication-driven exfoliation of aggregates and bundles of single-wall carbon nanotubes (SWNTs) in an aqueous surfactant solution can be easily monitored by UV-vis spectroscopy. The different stages of the exfoliation process were directly visualized by cryogenic temperature transmission electron microscopy, showing an excellent correspondence with the spec...

A new complex of Chromium(III) and the cross-bridged macrocyclic ligand 4,11-dimethyl-1,4,8,11tetraazabicyclo[6.6.2] hexadecane has been synthesized. Complexation of Tungsten, Vanadium, and Molybdenum was unsuccessful. The Cr(III)(L) complex was characterized using UV-Visible spectroscopy λmax = 583nm , IR Spectroscopy, X-Ray Crystallography, and magnetic susceptibility ueff = 3.95. These tests...

SPECTROELECTROCHEMICAL STUDIES OF METALLOPORPHYRINS IN ROOM TEMPERATURE IONIC LIQUID Yong Soo Hoo, B.A., M.S. Marquette University, 2010 The oxidation/reduction reactions of porphyrins and metalloporphyrins play an important role in medicinal, industrial and biochemical reactions. Metalloporphyrins are particularly useful as potential catalysts for a variety of processes including catalytic oxi...

Host-guest inclusion complexes of β-cyclodextrin with two vitamins viz., nicotinic acid and ascorbic acid in aqueous medium have been explored by reliable spectroscopic, physicochemical and calorimetric methods as stabilizer, carrier and regulatory releaser of the guest molecules. Job's plots have been drawn by UV-visible spectroscopy to confirm the 1:1 stoichiometry of the host-guest assembly....

F. Hendrick, B. Barret , M. Van Roozendael, H. Boesch , A. Butz, M. De Mazière, F. Goutail, C. Hermans, J.-C. Lambert, K. Pfeilsticker, and J.-P. Pommereau Institut d’Aéronomie Spatiale de Belgique (IASB-BIRA), Brussels, Belgium Institute for Environmental Physics, University of Heidelberg, Germany Service d’Aéronomie du CNRS, Verrieres le Buisson, France Now at: Service de Chimie Quantique et ...