The conversion of SO2 into arylsulfones under metal-free conditions was achieved for the first time by reacting SO2 with (hetero)arylsilanes and alkylhalides in the presence of a fluoride source. The mechanism of this transformation was elucidated based on DFT calculations, which highlight the influence of SO2 in promoting C-Si bond cleavage.

We discuss collection 2 SO2 data from the DutchFinnish Ozone Monitoring Instrument (OMI) on board NASA EOS/Aura spacecraft and show examples of detected volcanic and anthropogenic SO2 emissions. Quantification of anthropogenic SO2 emissions requires collection 3 reprocessing available in the fall 2007.

The present studies deals with the adsorption of SO2 by manganese oxide i.e., Pyrulusite ore. Pyrulusite is used as an adsorbent for the present studies. It is found that the percentage removal of SO2 increases with the increase in contact time, follows first order kinetics and a unimolecular layer is formed during the process. The percentage removal of SO2 increases with increase in dosages an...

This study evaluated in vivo imaging capabilities and safety of qualitative monitoring of oxygen saturation of hemoglobin (sO2) of rabbit ciliary body tissues obtained with acoustic resolution (AR) photoacoustic tomography (PAT). AR PAT was used to collect trans-scleral images from ciliary body vasculature of seven New Zealand White rabbits. The PAT sO2 measurements were obtained under the foll...

The removal of SO2 in the presence of alkene-ozone systems has been studied for ethene, cis-but-2-ene, trans-but-2-ene and 2,3-dimethyl-but-2-ene, as a function of humidity, under atmospheric boundary layer conditions. The SO2 removal displays a clear dependence on relative humidity for all four alkene-ozone systems confirming a significant reaction for stabilised Criegee intermediates (SCI) wi...

OBJECTIVE To evaluate the dynamics of skin microvascular blood flow (BF) and tissue oxygenation parameters (OXY) measured simultaneously at the same site using a combined non-invasive BF+OXY+temperature probe. METHODS Skin BF, oxygenated (oxyHb) and deoxygenated (deoxyHb) haemoglobin and mean oxygen saturation (SO2 ) were measured in 50 healthy volunteers at rest and during perturbation of lo...

The objective of this work is to develop a sustainable process for simultaneous removal of waste gases such as NO, NO2, and SO2 by an electrochemically generated Ag(I)/Ag(II) redox mediator system. High removal efficiency was achieved for NO and SO2 by the wet scrubbing method at room temperature and atmospheric pressure. This removal is achieved through oxidation and absorption by contacting t...

The global flux of sulfur dioxide (SO2) emitted by passive volcanic degassing is a key parameter that constrains the fluxes of other volcanic gases (including carbon dioxide, CO2) and toxic trace metals (e.g., mercury). It is also a required input for atmospheric chemistry and climate models, since it impacts the tropospheric burden of sulfate aerosol, a major climate-forcing species. Despite i...

Ground-level sulphur dioxide is one of the air pollutants of high concern as a typical indicator of urban air quality. To inform decisions regarding, for instance, the protection of public health from elevated SO2 levels in the city of Balikesir, an understanding of spatial-temporal variance of SO2 patterns is necessary. Therefore, the aim of this study is to locate sample points, characterize ...