We consider a quantum particle in an infinite square potential well of Rn, n = 2, 3, subjected to a control which is a uniform (in space) electric field. Under the dipolar moment approximation, the wave function solves a PDE of Schrödinger type. We study the spectral controllability in finite time of the linearized system around the ground state. We characterize one necessary condition for spec...

Residual dipolar couplings are being increasingly used as structural constraints for NMR studies of biomolecules. A problem arises when dipolar coupling contributions are larger than scalar contributions for a given spin pair, as is commonly observed in solid state NMR studies, in that signs of dipolar couplings cannot easily be determined. Here the sign ambiguities of dipolar couplings in fiel...

Dislocation dynamics simulations of the interaction between prismatic dipolar loops and a glide screw dislocation are presented. As a result of stress gradients generated by the glide dislocation, dipolar loops execute drift motion along their glide cylinders. Simulations of the combined motion of two dipolar loops in the stress field of a glide dislocation clearly show that inter-loop forces a...

A 13C-detected N-H dipolar coupling technique is introduced for uniaxially mobile membrane proteins for orientation determination using unoriented samples. For proteins undergoing rigid-body uniaxial rotation in the lipid bilayer, the intrinsic equality between the dipolar coupling constants measured in unoriented samples and the anisotropic coupling measured in static oriented samples has been...

The 1,3-dipolar cycloaddition of 3-nitro-2(1H)-quinolones with ester-stabilized azomethine ylides derived from sarcosine ester and various aromatic aldehydes has been investigated. structure stereochemistry cycloadducts were studied in detail by X-ray NMR spectroscopy methods.

Residual dipolar couplings and their corresponding alignment tensors are useful for structural analysis of macromolecules. The error in an alignment tensor, derived from residual dipolar couplings on the basis of a known structure, is determined not only by the accuracy of the measured couplings but also by the uncertainty in the structure (structural noise). This dependence is evaluated quanti...

DOI: 10.1002/aelm.201500070 simulations by Dvornik et al. [ 30 ] Recently, Keatley et al. [ 31 ] used a time-resolved scanning Kerr microscopy to isolate the dynamic dipolar interaction between a pair of nominally-shaped disks. However, a detailed scrutiny of phase-resolved Kerr ellipticity data is required to determine the dynamic dipolar coupling strength versus edge-to-edge spacing/diameter ...