A palladium composite membrane was prepared via electroless plating technique using organic-inorganic method during activation process. The ceramic support surface was modified by two TiO2-boehmite and one γ-alumina layers to avoid Pd penetration in support pores. Thin and defect-free Pd composite membrane was obtained by creating a relative smoothness on the ceramic support and using Pd nanopa...

The widely used Arrhenius equation describes the kinetics of simple two-state reactions, with the implicit assumption of a single transition state with a well-defined activation energy barrier DeltaE, as the rate-limiting step. However, it has become increasingly clear that the saddle point of the free-energy surface in most reactions is populated by ensembles of conformations, leading to nonex...

We report magnetoresistivity measurements on a La1:2Sr1:8Mn2O7 single crystal. The charge transport in the ferromagnetic phase is dominated by two-magnon scattering in the high T range and by weak localization effects at lower T ; in the non-metallic regime. In the paramagnetic phase, rabðTÞ obeys the adiabatic small polaron hopping mechanism, while rcðTÞ follows an Arrhenius behavior with the ...

The effects of temperature on the chloride-induced corrosion behavior reinforcing steel in simulated sea-sand concrete pore solution are studied by means linear polarization resistance. results show that Ecorr (corrosion potential) and icorr current density) steels and/or chloride concentration (CCl)-related parameters. A correlation between a natural logarithmic CCl observed. It is proved rela...

The hot deformation of TA15 titanium alloy was studied by the compression test on Gleeble-3800 thermal simulation equipment. true stress-strain curves at temperature 1123-1223K and strain rate 0.001-1s -1 were obtained.. results show that flow stress increases with decreasing temperature, as increases. And process is accompanied work hardening dynamic recovery recrystallization. Based alloy, Ar...

Ethanol is commonly used as a solvent in extracting glucomannan from Porang. However, the extraction process often leaves ethanol. The remaining ethanol can be re-distilled to save use of it. re-distillation with input volumes 50L and 100L variations heating temperatures 80°C, 85°C, 90°C. This study aimed analyze effect volume temperature on output determine constant change using kinetics Arrhe...

We have investigated the relationship between function and molecular dynamics of both the lipid and the Ca-ATPase protein in sarcoplasmic reticulum (SR), using temperature as a means of altering both activity and rotational dynamics. Conventional and saturation-transfer electron paramagnetic resonance (EPR) was used to probe rotational motions of spin-labels attached either to fatty acid hydroc...

We demonstrate that by utilizing an overscreened Josephson junction as a noise detector it is possible to achieve the threshold regime, whereby the tails of the fluctuating current distribution are measured. This situation is realized by placing the Josephson junction and mesoscopic conductor in an external circuit with very low impedance. In the underdamped limit, overscreening the junction in...

Introduction: Diffusion in brain tissue is well known to be non-Gaussian, resulting in major efforts to understand the biophysical basis of water mobility in such tissues [1]. This study aims to understand the energetics of differently diffusing components by quantification of their respective activation energies. When temperature is varied, self-diffusion in pure liquids follows the Arrhenius ...