The adsorption of asphaltenes onto flat solid surfaces modified with mixed self-assembled monolayers (SAMs) of aliphatic and aromatic trichlorosilanes with varying wettabilities, aromaticities, and thicknesses is tested. The mixed SAMs are characterized by means of contact angle to assess hydrophobicity and molecular and chemical uniformity, spectroscopic ellipsometry to measure the thickness o...

In this work the likelihood of asphaltene deposition problems during dynamic displacement of oil by natural gas in unconsolidated porous media is experimentally inspected. The two different rock materials, limestone and sandstone, are used as a representative of porous media. Dynamic flow experiments indicate that the increase of natural gas injection inc...

the basics of quantum mechanics and statistical thermodynamics were used to predict the potential energy and intermolecular forces of asphaltene molecules. the parameters associated with the chemical structure were also estimated for a specific asphaltene molecule to predict the mie potential function. based on the structural results, a new form of the virial eos with peneloux correction was de...

Asphaltene deposition is a common phenomenon during CO2 flooding in ultralow permeability reservoirs. The deposited asphaltene occupies the pore volume and decreases permeability, resulting serious formation damage well productivity. It urgent to investigate mechanisms, adverse effects, preventive measures. However, few investigations have been systematically conducted by now. In this research,...

The deposition of asphaltenes in porous media, an important problem in science and macromolecular engineering, was for the first time investigated in a transparent packed-bed microreactor (μPBR) with online analytics to generate high-throughput information. Residence time distributions of the μPBR before and after loading with ~29 μm quartz particles were measured using inline UV-Vis spectrosco...

This study investigates the effect of surface acidity and basicity of aluminas on asphaltene adsorption followed by air oxidation. Equilibrium batch adsorption experiments were conducted at 25°C with solutions of asphaltenes in toluene at concentrations ranging from 100 to 3000 g/L using three conventional alumina adsorbents with different surface acidity. Data were found to better fit to the F...

The basics of quantum mechanics and statistical thermodynamics were used to predict the potential energy and intermolecular forces of asphaltene molecules. The parameters associated with the chemical structure were also estimated for a specific asphaltene molecule to predict the Mie potential function. Based on the structural results, a new form of the Virial EOS with Peneloux correction wa...

The use of nanoparticles, including metal oxide surfaces, as asphaltene adsorbents is a potential method of removing and/or upgrading asphaltenes. The adsorption of two asphaltene types, extracted from two types of Iranian crude oil, onto nanoparticles (TiO2, SiO2, and Al2O3) are assessed and the thermal behavior of the adsorbed asphaltenes is examined under an oxidizing atmosphere through ther...

this paper is concerned with asphaltene deposition in fluid flowing through pipelines. brownian diffusion and drag, gravitational, thermophoresis, buoyancy, and shear removal are considered as possible mechanisms in the asphaltene deposition process. the thermo-physical properties of the fluid were obtained from iranian oil fields. a model was used in the pipeline deposition modeling to predict...

Abstract This research study aims to conduct a comparative performance analysis of different scaling equations and non-scaling models used for modeling asphaltene precipitation. The experimental data carry out this are taken from the published literature. Five which include Rassamadana et al., Rassamdana Sahimi, Hu Gou, Ashoori log–log were applied in two ways, i.e., on full dataset partial dat...