Developing efficient, low-cost, and stable carbon-based catalysts for oxygen reduction reaction (ORR) to replace the expensive platinum-based electrocatalysts remains a major challenge that hamper the practical application of fuel cells. Here, we report that N, Fe, and S co-doped nanoporous carbon material, derived via a facile one-step pyrolysis of sewage sludge, the major byproduct of wastewa...

Life is a persistent, self-specified set of far from equilibrium chemical reactions. In modern microbes, core carbon and energy metabolism are what keep cells alive. In very early chemical evolution, the forerunners of carbon and energy metabolism were the processes of generating reduced carbon compounds from CO(2) and the mechanisms of harnessing energy as compounds capable of doing some chemi...

Structure The radionuclide 99mTchas nearly ideal physical characteristics for imaging and is presently being used as a label for numerous radiopharmaceuticals. Consequently, most of the major organ systems have been studied with the aid of this radionuclide. One of the most recent to be considered is the skeletal system as reported by Subramanian and coworkers who labeled inorganic polyphosphat...

The application of organic-inorganic nanocomposite membranes allows for a synergy between the desirable thermal and mechanical properties inorganic materials with reactivity, dielectric properties, durability, flexibility, processability polymeric materials. Proton exchange membrane fuel cells (PEMFCs) suffer from some problems including water content management, carbon monoxide poisoning, hydr...

The field of uremic toxicity comprises the study of a large number of different substances, classified in relation to various characteristics, for example, protein-binding, dimensions, and so forth. The endogenous compounds of a gaseous nature have received much attention lately from the scientific community because of their increasingly recognized importance in health and disease. Among these ...

Records from lake sediment cores are critical for assessing the relative stability of climate and ecosystems over the Holocene. Duck Lake in south-central Lower Michigan, USA, was the focus of a study that identified how changes in the geochemical variables in lake sediments relate to variations in regional climate and local land use during the Holocene. More than 8.5 m of lacustrine sediment w...

" C 0 2 " exists in solution in the cytoplasm of cells predominantly as the hydrated and deprotonated form, HCO~, and also (albeit in smaller proportion) as the unhydrated, dissolved gas form, CO2 (Fig. 1). "CO2" fixation denotes the process of incorporation into organic matter of any form of the inorganic "CO2" compounds, and involves the establishment of a covalent bond between the carbon ato...

Landfilling is one of the most widely used methods for the disposal of municipal solid wastes. The degradation of the organic fraction of the wastes in combination with percolating rainwater leads to the generation of highly contaminated liquid, called leachate. Municipal landfill leachates typically contain high concentrations of inorganic compounds (ammonium and metals), as well as high level...

We compare the nature of copepod outfluxes of nonliving matter, the factors controlling their rate and their fate, and finally their role, particularly their relative importance in the carbon and nitrogen cycle. Copepods release dissolved matter through excretion and respiration and particulate matter through production of faecal pellets, carcasses, moults, and dead eggs. Excretion liberates se...

Methylidynetrisphosphonates are representatives of geminal polyphosphonates bearing three phosphonate (PO3H2) groups at the bridged carbon atom. Like well-known methylenebisphosphonates (BPs), they are characterized by a P-C-P backbone structure and are chemically stable mimetics of the endogenous metabolites, i.e., inorganic pyrophosphates (PPi). Because of its analogy to PPi and an ability to...