A simple synthetic method is presented for the precipitation of high purity, dry amorphous calcium carbonate (ACC) based on freeze-drying saturated, counter ion free CaCO3 solutions, where the ACC produced shows an extended atmospheric stability. Translation of the methodology to amorphous calcium phosphate demonstrates the generality of the approach.

The preparation of porous Mn2O3 boxes has been developed via a carbonate precursor route. As a Li-ion battery anode, it delivers a high reversible capacity of 1442 mA h g(-1) over 600 cycles at 800 mA g(-1), and 65% of the capacity originates from the gradually emerging interfacial storage contribution.

The interaction of the Li-ion battery solvent ethylene carbonate (EC) with Cu(111) was investigated by scanning tunnelling microscopy (STM) and variable temperature X-ray photoelectron spectroscopy (XPS) under ultrahigh vacuum (UHV) conditions. Between 80 and 420 K, the decomposition of EC occurs along with distinct structural and chemical changes of the adlayer.

The formation of the alkyl carbonate-derived solid electrolyte interphase (SEI) enables the use of active materials operating at very cathodic potentials in Li-ion batteries. However, the SEI in semi-solid flow batteries results in a hindered electron transfer between a fluid electrode and the current collector restricting the operating potentials to ca. 0.8 V vs. Li/Li(+) for EC-based electrol...

Carbonate mud is a major constituent of recent marine carbonate sediments and of ancient limestones, which contain unique records of changes in ocean chemistry and climate shifts in the geological past. However, the origin of carbonate mud is controversial and often problematic to resolve. Here we show that tropical marine fish produce and excrete various forms of precipitated (nonskeletal) cal...

[1] During the Paleocene‐Eocene thermal maximum (PETM ∼55 Myr ago), prominent climatic and biogeochemical changes took place in the atmosphere, ocean, and on land. For example, deep‐sea temperatures rose by 5°C to 6°C, while sea surface temperatures at high latitudes increased by up to 9°C. In the sedimentary record, the onset of the PETM is marked by widespread dissolution of calcium carbonate...

Potential applications of sodium-ion batteries in grid-scale energy storage, portable electronics and electric vehicles have revitalized research interest in these batteries. However, the performance of sodium-ion electrode materials has not been competitive with that of lithium-ion electrode materials. Here we present sodium manganese hexacyanomanganate (Na2MnII[MnII(CN)6]), an open-framework ...

OBJECTIVE To investigate the possible mode of action of a dentifrice containing 8% arginine and calcium carbonate (Pro-Argin Technology), and sodium monofluorophosphate in delivering the benefits of preventing acid erosion and rehardening acid-softened enamel. METHODS The surfaces of acid-softened bovine enamel specimens were evaluated after application of a dentifrice containing 8% arginine,...

Different methods for the functionalization of carbonate hydroxyapatite granules with free amine groups by reaction with (3-aminopropyl)triethoxysilane (APTES) have been compared in order to improve the potential for tethering of bioactive molecules to bioceramics. The combined use of tetraethoxyorthosilicate and APTES with acid catalysis resulted in an evident increase in amine surface grafting.

[1] Broecker and Clark [2002] use the ‘‘size normalized weight’’ of planktic foraminifera to estimate the carbonate ion concentration ([CO3 ]) of Atlantic glacial upper deep water. This method was introduced by Lohmann [1995] and is based on the fact that, within a defined size fraction, dissolution decreases shell weight in proportion to the degree of undersaturation with respect to CaCO3. On ...