In the previous studies, the several halocarbons (HC) were tested as promoters for a Ti-based Ziegler-Natta (ZN) catalyst at different polymerization conditions. The Results showed that chloro cyclohexane has the best operation in catalyst activity, polymer particle size growth, hydrogen responsibility and wax reduction too. For the first time in this study, the effect of Al/Ti ratio on the opt...

Nanophase Ti02 particles, with typical particle sizes in the range of 20-50 nm, have been synthesized using a microemulsion-mediated process. In this process, the aqueous cores ofwater/TritonX-100/exanol/ cyclohexane microemulsions have been used as constrained microreactors for the precipitation of precursor titanium hydroxide. The hydroxide particles thus formed were separated, dried, and cal...

Polystyrene resins with varied particle sizes (35 to 350-600 microm) and pore diameters (300-1000 A) were employed to study the effects of immobilization resin particle size and pore diameter on Candida antarctica Lipase B (CALB) loading, distribution within resins, fraction of active sites, and catalytic properties for polyester synthesis. CALB adsorbed rapidly (saturation time </= 4 min) for ...

XC-72 carbon supported Pt catalyst was prepared by using a microwave heated ethylene glycol method and characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). For comparison, the same Pt/XC72 catalyst was also prepared by conventional heated ethylene glycol method. TEM image showed that microwave synthesized Pt nanoparticles were uniformly dispersed on the surface o...

We present a novel heterogeneous Fenton-like catalyst of LiFePO4 (LFP). LFP has been widely used as an electrode material of a lithium ion battery, but we observed that commercial LFP (LFP-C) could act as a good Fenton-like catalyst to decompose rhodamine 6G. The catalytic activity of LFP-C microparticles was much higher than a popular catalyst, magnetite nanoparticles. Furthermore, we found th...

Pt-Ru supported on carbon nanotubes (CNTs) (single-walled nanotubes, double-walled nanotubes (DWNTs), and multi-walled nanotubes) catalysts are prepared by an ethylene glycol reduction method. Pt-Ru nanoparticles with a diameter of 2-3 nm and narrow particle size distributions are uniformly deposited onto the CNTs. A simple and fast filtration method followed by a hot-press film transfer is emp...

Concentrated livestock feeding operations have become a source of odorous gas emissions that impact air quality. Comprehensive and practical technologies are needed for a sustainable mitigation of the emissions. In this study, we advance the concept of using a catalyst for barn walls and ceilings for odor mitigation. Two catalysts, a new TiO2-based catalyst, PureTi Clean, and a conventional Evo...

Fenton oxidation, an advanced oxidation process, is an efficient method for the treatment of recalcitrant wastewaters. Unfortunately, it utilizes H2O2 and iron-based homogeneous catalysts, which lead to the formation of high volumes of sludge and secondary pollutants. To overcome these problems, an alternate option is the usage of heterogeneous catalyst. In this study, a heterogeneous catalyst ...

Porosity in catalyst particles is essential because it enables reactants to reach the active sites and it enables products to leave the catalyst. The engineering of composite-particle catalysts through the tuning of pore-size distribution and connectivity is hampered by the inability to visualize structure and porosity at critical-length scales. Herein, it is shown that the combination of phase...

piroxicam has two different crystalline forms (known as needle and cubic forms), that they are different in physicochemical properties such as biological solubility. in the current research, using taguchi experimental design approach the influences of five operating variables on formation of the piroxicam polymorph shapes in recrystallization were studied. the variables include type of solvent,...