Gasification of pyrolysis oil was studied in a fluidized bed over a wide temperature range (523-914 °C) with and without the use of nickel-based catalysts. Noncatalytically, a typical fuel gas was produced. Both a special designed fluid bed catalyst and a crushed commercial fixed bed catalyst showed an initial activity for syngas (H2 and CO) production at T >700 °C. However, these catalysts los...

  In this paper, modeling and optimization of Fischer-Tropsch Synthesis is considered in a fixed-bed catalytic reactor using an industrial Fe-Cu-K catalyst. A one dimensional pseudo-homogenous plug flow model without axial dispersion is developed for converting syngas to heavy hydrocarbons. The effects of temperature, pressure, H2 to CO ratio in feed stream, and CO molar flow on the mass flow r...

We present the design and performance of a homebuilt high-pressure and high-temperature reactor equipped with a high-resolution scanning tunneling microscope (STM) for catalytic studies. In this design, the STM body, sample, and tip are placed in a small high pressure reactor ( approximately 19 cm(3)) located within an ultrahigh vacuum (UHV) chamber. A sealable port on the wall of the reactor s...

The effects of confinement in carbon nanotubes on Fischer-Tropsch (FT) activity, selectivity and lifetime of Carbon NanoTubes (CNTs) supported iron catalysts are reported. A method was developed to control the position of the catalytic sites on either inner or outer surface of carbon nanotubes. TEM analyses revealed that more than 80% of iron oxide particles can be controlled to be position...

We demonstrate the preparation and characterization of a simplified packed-bed microreactor using an immobilized TEMPO catalyst shown to oxidize primary and secondary alcohols via the biphasic Anelli-Montanari protocol. Oxidations occurred in high yields with great stability over time. We observed that plugs of aqueous oxidant and organic alcohol entered the reactor as plugs but merged into an ...

This work introduces a biochar as novel catalyst prepared from the pistachio hull, and demonstrates its catalytic potential for degrading the reactive red 198 (RR198) dye in catalytic ozonation processes (COPs). The prepared pistachio hull biochar (PHB) was a macroporous, basic material with low specific surface area. PHB had the greatest catalytic potential at an optimal alkaline pH of 10. Sig...

Nitrous oxide (N2O) has been recognized as a relatively strong greenhouse gas. Heterogeneous catalytic processes have been mainly used to decompose N2O at high temperature. Characteristics of N2O decomposition by catalyst-assisted cold plasma were investigated in the present study. Tubular quartz reactor with annular-shaped electrodes was prepared and ruthenium catalysts supported on alumina pe...