Engineering a bimetallic system with complementary chemical properties can be an effective way of tuning catalytic activity. In this work, CO oxidation on CeO2(111)supported Pd-based bimetallic nanorods was investigated using density functional theory calculations corrected by on-site Coulomb interactions. We studied a series of CeO2(111)supported Pd-based bimetallic nanorods (Pd−X, where X = A...

A&met-Non-stoichiometric manganese dioxide prepared electrochemically at room temperature and suspended in dilute sulphuric acid is used to oxidise isosafrole to piperonal in 54% isolated yield. The manganese dioxide-manganese@) sulphate system can be recycled electrochemically at high current density. It has the further advantage that water-soluble materials derived from the chemical oxidation...

We report on the successful fabrication of silicon quantum wires with SiO 2 boundaries on SiGe/Si heterostructures by combining Si/SiGe/Si heteroepitaxy, selective chemical etching, and subsequent thermal oxidation. The observational result of scanning electron microscope is demonstrated. The present method provides a well-controllable way to fabricate silicon quantum wires. PACS: 81.15; 81.60;...

background and aim: 2,4-dichlorophenol (dcp) is a compound  generated in a variety of industrial processes and also by chlorine disinfection of water polluted with phenolic compounds . dumping of dcp into the environment and water resources is of great concern because of the compound's intense odor and toxicity. dcp is very soluble and resistant to biodegradability so it cannot be removed ...

Pyrolysis of solid fuels forms a carbon-rich fuel, also called char, whose physico-chemical description is rather complex. Heterogeneous oxidation reactions take place during thermochemical conversion char. The present work proposes predictive detailed kinetic model, opening new path for deeper understanding the char process. This model considers porosity, surface area, density sites, and their...

Hydroxylamines gradually undergo oxidation to their oximes on being dissolved in organic solvent (e.g. methanol). This phenomenon was followed by (1)H-NMR and liquid chromatography-mass spectrometry (LC-MS). The oxidation rate was estimated from the peak area observed on the mass chromatogram at the protonated molecule or fragment ion on LC-atmospheric pressure chemical ionization (APCI)-MS. Th...