Thermo-exfoliated graphite (TEG)/CuO/Cu2(OH)3NO3:(Co/Fe) composites were prepared using a wet impregnation method and subsequent thermal treatment. The physicochemical characterization of the composites was carried out by powder X-ray diffraction (PXRD), scanning electron microscopy (SEM) and Ar temperature-desorption techniques. The catalytic efficiency toward CO conversion to CO2 was examined...

Relating the observed CO emission from giant molecular clouds (GMCs) to the underlying H2 column density is a long-standing problem in astrophysics. While the Galactic CO–H2 conversion factor (XCO) appears to be reasonably constant, observations indicate that XCO may be depressed in high surface density starburst environments. Using a multiscale approach, we investigate the dependence of XCO on...

Oxygen conversion process between O₂ and H₂O by means of electrochemistry or photochemistry has lately received a great deal of attention. Cobalt-phosphate (Co-Pi) catalyst is a new type of cost-effective artificial oxygen-evolving complex (OEC) with amorphous features during photosynthesis. However, can such Co-Pi OEC also act as oxygen reduction reaction (ORR) catalyst in electrochemical proc...

Abstract Clostridium autoethanogenum, the bacterial model for biological conversion of waste gases into biofuels, grows under extreme carbon-monoxide (CO) concentrations. The strictly anaerobic bacterium derives its entire cellular energy and carbon from this poisonous gas, therefore requiring efficient molecular machineries CO-conversion. Here, we structurally biochemically characterized key e...

A very efficient electrogenerated Fe(0) porphyrin catalyst was obtained by substituting in tetraphenylporphyrin two of the opposite phenyl rings by ortho-, ortho'-phenol groups while the other two are perfluorinated. It proves to be an excellent catalyst of the CO2-to-CO conversion as to selectivity (the CO faradaic yield is nearly quantitative), overpotential, and turnover frequency. Benchmark...

An improved formulation for the N(H 2)/I(CO) conversion factor or X-factor is proposed. The statement that the velocity-integrated radiation temperature of the 12 CO J = 1 → 0 line, I(12 CO), " counts " optically thick clumps is quantified using the formalism of Martin et al. (1984) for line emission in a clumpy cloud. Adopting the simplifying assumptions of thermalized 12 CO J = 1 → 0 line emi...

Electrochemical carbon dioxide (CO2) conversion technologies have become new favorites for addressing environmental and energy issues, especially with direct electrocatalytic reduction of CO2 (ECO2RR) alkali metal-CO2 (M–CO2) batteries as representatives. They are poised to create economic drivers while also paving the way a cleaner more sustainable future humanity. Although still far from prac...

The structural properties and activities of Cu-Co catalysts used in Fischer-Tropsch synthesis are explored according to their method of preparation. Impregnation, co-precipitation, and a novel method of thermal decomposition were applied to an inorganic precursor complex to generate the Cu-promoted alumina- and silica-supported cobalt catalysts. The precursors and the catalysts obtained by ...