A palladium membrane was prepared using the electroless plating technique (ELP) for the separation and purification of hydrogen from a gas mixture. Depending on operating conditions, hydrogen flux from the membrane was in the range of 0.012-0.023 mol.m-2.s-1. The membrane performance in the presence of CO2 was investigated. The results of the GC analysis showed that at a feed concentration of 1...

Separation of CO2 involving mixtures is relevant to the various industrial settings and preserving environment for which different classes materials including metal-organic frameworks (MOFs) have been researched. Herein, CO2/CO, CO2/H2, CO2/N2, H2S/CO2 separation properties zirconium MOFs are computationally investigated mimicking vacuum swing adsorption (VSA) process. Structure-performance rel...

Chemical-Looping Combustion (CLC) is an emerging technology for CO2 capture because separation of this gas from the other flue gas components is inherent to the process and thus no energy is expended for the separation. Natural or refinery gas can

A novel physical (non-reactive) separation of cellulose from an ionic liquid (IL)/cosolvent mixture by compressed carbon dioxide is presented. The precipitation is completely reversible and rapid within small changes of pressure i.e. liquid phase CO2 composition. High pressure phase equilibrium, high pressure NMR, and solid state NMR have been utilized to understand the separation phenomena.

Introduction of closed cycle gas turbines with their capability of retaining combustion generated CO2 can offer a valuable contribution to the Kyoto goal and to future power generation. Therefore research and development at Graz University of Technology since the 90's has lead to the Graz Cycle, a zero emission power cycle of highest efficiency. It burns fossil fuels with pure oxygen which enab...