A 3D porous framework [Co3(μ2-OH)4(I)2]·2H2O (I = hypoxanthine) with two types of 1D channels possess excellent catalytic ability for the selective oxidation of cis-cyclooctene.

Chemical precipitation to form magnesium ammonium phosphate (MAP) is an effective technology for recovering ammonium nitrogen (NH4(+)-N). In the present research, we investigated the thermodynamic modeling of the PHREEQC program for NH4(+)-N recovery to evaluate the effect of reaction factors on MAP precipitation. The case study of NH4(+)-N recovery from coking wastewater was conducted to provi...

Three novel tetrazole-based frustrated magnets, namely, Co3(OH)2(3-ptz)2(SO4)(H2O)4 (1), Co2(OH)(tzba)(H2O)4 (2) and [Co(OH)(tta)] (3) (3-ptz = 5-(3-pyridyl) tetrazole, H2tzba = 4-(1H-tetrazol-5-yl) benzoic acid, Htta = 1H-tetrazole) were hydrothermal synthesized and magnetically characterized. Compound 1 is a 2D (4,4) layered structure assembled by sulfate capped triangular [Co3(μ3-OH)(μ3-SO4)...

A CO3(2-)-panelled [Gd(III)6Cu(II)3] cage conforming to a tridiminished icosahedron is synthesised by bubbling CO2 through a solution of Gd(III) and Cu(II) ions.

Pedogenic goethites in each of two Early Permian paleosols appear to record mixing of two isotopically distinct CO2 components—atmospheric CO2 and CO2 from in situ oxidation of organic matter. The C values measured for the Fe(CO3)OH component in solid solution in these Permian goethites are 13.5‰ for the Lower Leonardian ( 283 Ma BP) paleosol (MCGoeth) and 13.9‰ for the Upper Leonardian ( 270 M...

The complex cation of the title compound, [Co(CO3)(C10H8N2)2]2(C12H10N2O6)·6H2O, contains a Co(III) atom with a distorted octa-hedral coordination environment formed by four N atoms from two bidentate 2,2'-bi-pyridine ligands and one bidentate carbonate anion. The asymmetric unit is completed by one-half of the 2-({4-[(carboxyl-atometh-yl)carbamo-yl]phen-yl}formamido)-acetate dianion, which is ...

A new synthesis of 1,1,1-tris(pyrid-2-yl)ethane (L), and a survey of its coordination chemistry, are reported. The complexes [ML2](n+) (M(n+) = Fe(2+), Co(2+), Co(3+), Cu(2+) and Ag(+)), [PdCl2L] and [CuI(L)] have all been crystallographically characterised. Noteworthy results include an unusual square planar silver(i) complex [Ag(L)2]X (X(-) = NO3(-) and SbF6(-)); the oxidative fixation of aer...

A newly designed Co(II) complex, [Co3(L)(OAc)2(CH3OH)2]·CH3OH, by the reaction of a bis(salamo)-type tetraoxime ligand (H4L) with Co(II) acetate tetrahydrate was synthesized and characterized by elemental analyses, IR, UV-vis spectra and single-crystal X-ray crystallography. The UV-vis titration experiment manifested that a trinuclear (L:M = 1:3) complex was formed. It is worth noting that the ...

Cyclic voltammetric studies were carried out on the deposition of polyaniline on pure aluminum from oxalic acid solution with and without different anions (CO3, SO3, SO4, DBS) and contribution of these anions to lyaniline film formation was investigated. Corrosion behavior of polyaniline coated aluminum in oxalic acid solution with and without different anions (CO3, SO3, SO4, DBS) has been inve...