Calcined coke is a competitive material for making carbon anodes for smelting of alumina to aluminum. Calcining is an energy intensive industry and a significant amount of heat is exhausted in the calcining process. Efficiently managing this energy resource is tied to the profit margin and survivability of a calcining plant. To help improve the energy efficiency and reduce natural gas consumpti...

Exploring the associations between genetic polymorphisms of metabolic enzymes and susceptibility to polycyclic aromatic hydrocarbon (PAH)-induced chromosomal damage is of great significance for understanding PAH carcinogenesis. Cytochrome P450, glutathione S-transferase, microsomal epoxide hydrolase, NAD(P)H:quinone oxidoreductase, and N-acetyltransferase are PAH-metabolizing enzymes. In this s...

BACKGROUND The incidence of hospital admissions for respiratory and cardiovascular diseases in areas close to operating coke works in England and Wales was investigated. METHODS A small area study using distance from source as a proxy for exposure was undertaken in subjects aged 65 or over and children under 5 years within 7.5 km of four coke works (1991 estimated populations 87 760 and 43 93...

The run length of cracking furnaces is limited by the formation of coke on the internal skin of the reactor tubes. The reaction mechanism of thermal cracking of hydrocarbons is generally accepted as free-radical chain reactions. On the basis of the plant output data and the insight in the mechanisms for coke formation in pyrolysis reactors, a kinetic model describing the coke formation has been...

Dustfall measurements in Primorsko-goranska county started in 1975 in the Bakar Bay (Site 2 - Bakar and Site 3 - Kraljevica). The measurements were extended to the city of Rijeka (Site 1 - Rijeka) in 1982, to the nearby islands (Site 4 - Krk and Site 5 - Cres) in 1986, and inland to Gorski Kotar (Site 6 - Delnice and Site 7 - Lividraga) in 1995. This article brings the results of dustfall measu...

The kinetic modeling of the hydrocracking a mixture polystyrene (PS) and vacuum gasoil (VGO) over PtPd/HY catalyst has been carried out. reactions have performed in batch reactor under following conditions: 380–420 °C; 80 bar; content PS feed, 10 wt%; catalyst/feed ratio, 0.1 mass; time, 30–300 min. Different reaction networks models studied, which evolution product distribution (unconverted PS...

Different g-C3N4 composite systems (coke carbon/g-C3N4, Bi/Bi2WO6/g-C3N4 and Bi/Bi2MoO6/g-C3N4) have been assessed as photocatalysts for wastewater pollutants removal. The coke carbon/g-C3N4 hybrid, produced by thermal treatment at 550 °C of a composite made from melamine cyanurate and coke, only showed activity under UV-light irradiation. On the other hand, inorganic Bi spheres/Bi mixed oxides...

The catalytic dehydrogenation (DH) and oxidative dehydrogenation (ODH) of light alkanes are of significant industrial importance. In this work both carbonaceous material deposited on VOx/Al2O3 catalysts during reaction and unsupported carbon nanofibres (CNFs) are shown to be active for the dehydrogenation of butane in the absence of gas-phase oxygen. Their activity in these reactions is shown t...

Abstract Herein, the promotion effect of only 0.3 wt% indium on 3% Ni/Al2O3 and Ni/CeO2-Al2O3 catalysts prepared by deposition-precipitation over a commercial alumina CeO2-modified support was studied. Catalyst characterization XRD, TPR, XPS, TEM, CO-DRIFTS performed. The catalytic properties were investigated coke formation analyzed under temperature ramped CH4-decomposition in Dry Reforming M...

Introduction FCC decant oil is the primary feedstock to delayed coker to produce needle coke, a premium carbon precursor to synthetic graphite electrodes. Mesophase development during coking, determines the graphitizability of the needle coke product. Mesophase development, in turn, depends on the molecular composition of the feedstocks [1,2]. In a commercial delayed coking unit, liquid-phase c...