The water soluble photoinitiator (PI) 4-(trimethyl ammonium methyl) benzophenone chloride is used for the first time in the synthesis of silver nanoparticles (AgNPs). A new green synthesis method involves using PI/UV system, carboxymethyl starch (CMS), silver nitrate, and water. A mechanism of the reduction of silver ions to AgNPs by PI/UV system as well as by the newly born aldehydic groups wa...

Preparation of silver-alginate nanocomposite films as an antibacterial material has been carried out through the casting method colloidal silver-alginate. Colloidal was made by chemical reduction AgNO 3 precursor salts using microwave irradiation with alginate a stabilizer and reducing agent NaOH accelerator. The appearance brownish yellow color, due to addition variation , localized surface pl...

Alveolar macrophages of the beige mouse mutant have a system of smooth-surfaced elements with the hallmarks of GERL. GERL also appears to produce residual bodies, and both organelles show cytochemically demonstrable acid phosphatase activity. When cells are exposed to colloidal silver, the tracer is endocytosed via pinocytic vacuoles to GERL.

Raman, IR, and surface-enhanced Raman scattering (SERS) were employed for the vibrational characterization of papaverine in the free and adsorbed state. The vibrational assignments were performed by means of density functional theory (DFT) calculations. The adsorption of the molecule was concluded with the isoquinoline and the benzene ring close to the silver surface in tilted orientations. Emp...

According to the increased probability of the presence of nanomaterials in the aquatic ecosystems, the present study examined the toxicity of three engineered silver nanoparticles (AgNPs) as well as silver ions in the Pontogammarus maeoticus, a brackish water benthic organism living in the littoral zone of the Caspian Sea. The animals were acutely exposed to different concentrations of two comm...

A new method is proposed for the simple preparation of random silver micro and nano-electrode arrays. This employs acoustic streaming directed at a glassy carbon surface to "mechanically" attach particles from a suspension of metal colloidal or other small particles. The particles tend to adhere to the substrate at points of imperfection such as scratches, crevices etc. These arrays are compare...

In this paper we investigate the possibility to apply the concepts of non-specific intermolecular interactions and dispersive local field effect approach for study of the influence of interactions of metal nanoparticles with matrix molecules on the spectral characteristics of composites. The effect of intermolecular (interparticle) interactions and the influence of the dielectric environment on...

As innovations continue to be made in the fields of microfluidics and the colloidal assembly, new strategies for moving particles and fluids may be needed. Heterogeneous catalysis provides means of locally converting the stored chemical energy of fuels to mechanical energy. We report an ambient temperature stationary "pump" that generates a proton concentration gradient through the bipolar elec...

The existence of a metastable state with limited Coulomb-blocked aggregation at the onset of instability in a colloidal solution is proposed and demonstrated both experimentally and theoretically (through Monte Carlo simulations). Such a stable state of small clusters of metallic colloids happens to be extremely important for techniques such as surface-enhanced Raman scattering (SERS), which pr...

We report the results of treating a dense, chemically produced silver colloidal suspension with high-power laser pulses and with exposure to supercritical water (SCW) conditions. The initial colloid has a mean particle diameter measured by transmission electron microscopy to be 28.4 nm and exhibits a broad absorption band in the visible region with a small maximum near 420 nm. Both treatments r...