Changes in the linear attenuation coefficient of polymer gel dosimeters post-irradiation enable the imaging of dose distributions by x-ray computed tomography (CT). Various compositions of polymer gel dosimeters manufactured from acrylamide (AA), and N,N'-methylene-bis-acrylamide (BIS) comonomers and gelatin or agarose gelling agents were investigated. This work shows that increasing the comono...

A difunctional NLO Azo-Dye chromophore has been synthesized and polymerization has been performed with a comonomer bearing a side-chain epoxy group. Deposition of the polymer on glass substrates was performed by spincoating, resulting in uniform films up to 2 μm thickness. The orientation of the chromophore was performed under a “pinto-plane” positive corona discharge followed by a heat-treatme...

Three-dimensional (3D) microperiodic scaffolds of poly(2-hydroxyethyl methacrylate) (pHEMA) have been fabricated by direct-write assembly of a photopolymerizable hydrogel ink. The ink is initially composed of physically entangled pHEMA chains dissolved in a solution of HEMA monomer, comonomer, photoinitiator and water. Upon printing 3D scaffolds of varying architecture, the ink filaments are ex...

Chain-growth polymerizations are popular methods because they allow synthesis of highmolecular weight polymers in high yields and in short times. However, copolymers prepared by such processes generally exhibit uncontrolled monomer sequences. The controlled radical copolymerization of styrene with N-substituted maleimides is an interesting exception allowing preparation of controlled primary st...

Waveguides made of poly-methyl-methacrylate (PMMA) play a major role in the homogeneous distribution of display backlights as a matrix for solid-state dye lasers and polymer optical fibers (POFs). PMMA is favored because of its transparency in the visible spectrum, low price, and well-controlled processability. Nevertheless, technical drawbacks, such as its limited temperature stability, call f...

The control over comonomer sequences is barely studied in macromolecular science nowadays. This is an astonishing situation, taking into account that sequence-defined polymers such as nucleic acids and proteins are key components of the living world. In fact, fascinating biological machines such as enzymes, transport proteins, cytochromes or sensory receptors would certainly not exist if evolut...

Cylindrical elastomers were prepared through the UV-initiated crosslinking of terminally acrylated, 8,000 Da star-poly(trimethylene carbonate-co-ε-caprolactone) and star-poly(trimethylene carbonate-co-D,L-lactide). These elastomers were implanted intramuscularly into the hind legs of male Wistar rats to determine the influence of the comonomer on the weight loss, tissue response, and change in ...

Polyesters of xylitol and succinic acid were prepared yielding from 70 to 75% by enzymecatalyzed esterification using a molar mass 1:1 2:5 at 120 140 °C employing 1 10% m/m enzyme. Control over branching degree was achieved tuning the reaction conditions (temperature, time, comonomer ratio, enzyme content). This one-step process renewable starting materials avoids protection-deprotection techni...

Relationships between chiroptical properties (Optical Rotatory Dispersion, ORD, and Circular Dichroism, CD) and Conformation of structur— ally simple isotactic polymers and copolymers derived from optically active monomers are reviewed. Both experimental and calculated values fit with chain cotiformations consisting prëdomirantly of one screw sense helical sections due to dissyinmetric cooperat...

A series of titanium and zirconium complexes with ligands based on di-isopropyl phosphorus-phenylamine and their derivatives were synthesized and characterized. These catalysts were utilized to catalyze the copolymerization of ethylene with N-acetyl-O-(dec-9-enyl)-L-tyrosine ethyl ester with high catalytic activity of 6.63 × 104 g P (mol Ti)−1 h−1 after activation by methylaluminoxane (MAO). Th...