Nonradiative energy dissipation in electronically excited polyatomic molecules proceeds through conical intersections, loci of degeneracy between electronic states. We observe a marked enhancement of laser-induced double ionization in the vicinity of a conical intersection during a non-radiative transition. We measured double ionization by detecting the kinetic energy of ions released by laser-...

The present work is concerned with a numerical study of the performance of a conical annular centrifugal contractor through the analysis of the flow properties when the apex angle is changed for different imposed axial flows. The calculations revealed the advantage of using conical annular centrifugal contractors compared to the cylindrical annular centrifuges. The study is conducted by a compa...

We consider tessellations of the Euclidean (d− 1)-sphere by (d− 2)-dimensional great subspheres or, equivalently, tessellations of Euclidean d-space by hyperplanes through the origin; these we call conical tessellations. For random polyhedral cones defined as typical cones in a conical tessellation by random hyperplanes, and for their dual cones, we study expectations of certain geometric funct...

Finite conical electrodes, which are of particular interest as probes for imaging of surfaces using scanning electrochemical microscopy (SECM), in kinetic studies and in probing thin films were investigated. Theoretical SECM tip current-distance feedback (approach) curves for a finite conical electrode were calculated by numerical (finite element) analysis and compared to an earlier approximate...

Conical polynomials are defined as certain polynomials in quadratic elements of the universal enveloping algebra of a semisimple symmetric Lie algebra over a field of characteristic zero. These polynomials were used in an earlier paper to describe the conical vectors in certain induced modules. Here it is shown that when the base field is extended to a certain type of nonassociative algebra, th...

This study deals with the vibrational behavior of two joined cross-ply laminated conical shells. Natural frequencies and mode shapes are investigated. Joined conical shells can be considered as a general case for joined cylindrical-conical shells, joined cylinderplates or cone-plates, cylindrical and conical shells with stepped thicknesses and also annular plates. Governing equations are obtain...

Estimating the intrinsic dimension of a high-dimensional data set is a very challenging problem in manifold learning and several other application areas in data mining. In this paper we introduce a novel local intrinsic dimension estimator, conical dimension, for estimating the intrinsic dimension of a data set consisting of points lying in the proximity of a manifold. Under minimal sampling as...

We consider a class of semilinear elliptic problems in twoand three-dimensional domains with conical points. We introduce Sobolev spaces with detached asymptotics generated by the asymptotical behaviour of solutions of corresponding linearized problems near conical boundary points. We show that the corresponding nonlinear operator acting between these spaces is Fréchet differentiable. Applying ...

Presenting true crossings of adiabatic potential energy surfaces, conical intersections are a paradigm of ultrafast and efficient electronic relaxation dynamics. The same mechanism is shown to apply also for vibrational conical intersections, which may occur when two high-frequency modes (such as OH stretch vibrations) are coupled to low-frequency modes (such as hydrogen bonding modes). By deri...