Cefpirome, which is a fourth-generation cephalosporin, was analyzed for the first time at glassy carbon electrode using differential pulse voltammetry in this novel method. Different experimental conditions were optimized, such as pH and electrolyte type, to achieve high peak current. Under optimum conditions, oxidation of cefpirome exhibited diffusion-controlled process depending on pH. Cefpir...

glassy carbon (gc) is the most commonly used carbon-based electrode in the analytical laboratory. because of the high background current and low electrode response, modification of this electrode can be done by various materials and techniques. an ionic liquid (il), 1-methyl-3-(3-trimethoxysilyl propyl) imidazoliumbis (trifluoromethylsulfonyl) imide, was covalently cross linked onto the gc surf...

The electrochemical behaviour of ebastine was studied at hanging mercury drop electrode using cyclic voltammetry and differential pulse voltammetry. The molecule shows a single, well defined reduction peak due to the reduction of carbonyl group. The voltammetric conditions were optimized with respect to maximum peak signals. The linearity between the peak signal and the concentration of ebastin...

Differential pulse voltammetry (DPV) and adsorptive stripping voltammetry (AdSV) at a hanging mercury drop electrode (HMDE) was used for the determination of trace amounts of carcinogenic nitrobiphenyls, namely 2-nitrobiphenyl (2-NBP), 3nitrobiphenyl (3-NBP) and 4-nitrobiphenyl (4-NBP) within the concentration range from 2.10 to 1.10 mol⋅L for DPV and from 2.10 to 1.10 mol⋅L for AdSV using a Br...

The small molecules NO and CO are known to mediate many physiological processes related to neurology , immunology, and muscle cell action. Electrochemical detection is often considered one of the most sensitive methods of detection, in our case exceeding nanomolar concentrations. In this study we married the technology of silicon planar with self-assembled monolayer membrane modified electrodes...

The antioxidant capacity of essential oils of Mentha spicata L., Mentha x gentilis L., Mentha crispa L., Mentha piperita L. and Mentha x piperita L. was determined by using differential pulse voltammetry. This assay was based on the reduction in the limiting current value of the oxygen electroreduction, which was used to calculate the antioxidant capacity (K) of these species. The species M. x ...

Electrochemical detection of quantum dots (QDs) has already been used in numerous applications. However, QDs have not been well characterized using voltammetry, with respect to their characterization and quantification. Therefore, the main aim was to characterize CdTe QDs using cyclic and differential pulse voltammetry. The obtained peaks were identified and the detection limit (3 S/N) was esti...

Cyclic voltammetry (CV) and differential pulse voltammetry (DPV) were performed with a glassy carbon electrode (GCE) modified with polyglutamic acid (PGA) on the three dihydroxybenzene isomers, catechol (CT), hydroquinone (HQ), and resorcinol (RS). At bare GCE, these isomers exhibited voltammograms with highly overlapped redox peaks that impeded their simultaneous detection in binary and ternar...