Various isotope studies require accurate fractionation factors (a’s) between different chemical compounds in thermodynamic equilibrium. Although numerous isotope systems involve aqueous solutions, the conventional theory is formulated for the gas-phase and predicts incorrect a’s for many compounds dissolved in water. Here I show that quantum-chemistry calculations, which take into account solut...

Models were developed for prediction and interpretation of the observed steady-state axial dissolved oxygen concentration profiles in tall airlift bioreactors. The observed concentration profiles were non-linear because of a combination of hydrodynamic and mass transport factors. The profiles were influenced mainly by the liquid-phase axial dispersion coefficient, the volumetric overall gas–liq...

When a nitrobenzene (NB) phase came in quiescent contact with a water phase, water-droplets were formed spontaneously near the oil|water interfaces (Electrochem. Commn. 11 (2009) 239). We reported here quantitative data of the NB-droplets by use of UV-absorbance, dynamic light scattering (DLS) and voltammetry with a help of ferrocene. The supernatant separated spontaneously from the oil-water m...

Trace element distribution was monitored for Uluabat lake water polluted with point and non-point sources in Bursa. An examination of Zn, Cr, Ni, Cu, Pb, As, B concentrations during the study period indicated that the particulate phase at the bottom of the water column were high in regard to dissolved phase. The source of trace elements in the deeper parts of the water column was derived from t...

in this study, porous scaffolds from poly(d,l-lactic acid) have been prepared via liquid- liquid phase separation method in ternary system of polymer-1,4-dioxane-water. polymer dissolved in dioxane in 1.5, 2.5 and 5 % wt/v and the solvent/non-solvent ratios were 13/87, 15/85 and 17/83. cloud point curves prepared by visual turbidometry. in order to obtain porous scaffolds with inter-connected p...

As a novel approach to characterize the phenolic pollutants of Lake Balaton (Central Europe, western Hungary), 26 endocrine disrupting phenols (chlorophenols, nitrophenols, alkylphenols, triclosan, bisphenol-A) were quantified in dissolved and suspended particulate matter (SPM) phases, alike. Sample collection was performed in the western and eastern basins, at 20 sites in April and October 201...

The electrochemical behavior of ZnTe and CdTe compound semiconductors dissolved in molten ZnCl(2) and equimolar CdCl(2)-KCl, respectively, was examined. In these melts dissolved Te is present as the divalent telluride anion, Te(2-), which was found able to be converted to elemental metal by electrochemical oxidation at the anode. ZnTe-ZnCl(2) melts were studied at 500 °C by standard electrochem...