key words: Lead corrosion, Raman spectroscopy, oxide reduction, organic acids, electrochemistry Even though kept in cultural institutions, artefacts can be subjected to accelerated deterioration due to high concentration of pollutants in closed spaces. Potentially harmful conditions have been evaluated by electrochemical reduction of corrosion products formed on metallic coupons which have been...

The inhibiting effect of drugs towards the corrosion of different metals and alloys has been reviewed in this paper. Results of Weight loss method, Potentiodynamic polarization and Electrochemical impedance spectroscopy were investigated. Kinetic and thermodynamic parameters provide valuable information about the mechanism of corrosion inhibition. Different classes of drugs, having hetero-atoms...

Three Mg alloys, Mg-1.34% Ca-3% Zn (MCZ), Mg-1.34% Ca-3% Zn-0.2% Sr (MCZS), and Mg-2% Sr (MS), were examined to understand their bio-corrosion behavior. Electrochemical impedance spectroscopy and polarization scans were performed after 6 days of immersion in cell culture medium, and ion release and changes in media pH were tracked over a 28 day time period. Scanning electron microscopy (SEM) of...

The effects of metallurgical factors on the aqueous corrosion behavior of highentropy alloys (HEAs) are reviewed in this article. Alloying (e.g., Al and Cu) and processing (e.g., heat treatments) effects on the aqueous corrosion behavior of HEAs, including passive film formation, galvanic corrosion, and pitting corrosion, are discussed in detail. Corrosion rates of HEAs are calculated using ele...

Copper-bearing intrauterine devices(Cu-IUDs) are being increasingly used all over the world. However, the dissolution of copper in the presence of proteins is not well characterized. Here, with open circuit potential, electrochemical impedance spectroscopy measurements and potentiodynamic polarization test, the corrosion behavior of copper samples in different single-protein simulated uterine s...

Hydrostatic pressure effects on pitting initiation and propagation in X70 steel are investigated by evaluating metastable pitting probability using electrochemical methods and immersion corrosion tests in containing chlorine ion solution. Potentiodynamic tests indicated that hydrostatic pressure can decrease the breakdown potential and lead to a reduced transpassivity region. Metastable test re...

Diabetes and infections are associated with a high risk of implant failure. However, the effects of such conditions on the electrochemical stability of titanium materials remain unclear. This study evaluated the corrosion behavior of a Ti-6Al-4V alloy, with a smooth surface or conditioned by double-acid-etching, in simulated body fluid with different concentrations of dextrose and lipopolysacch...

Two unlike metals near one another can break down as they move toward electrochemical equilibrium resulting in galvanic corrosion. We describe a case of electrochemical corrosion resulting in pseudarthrosis, followed by instrumentation failure leading to subarachnoid hemorrhage. A 53-year-old female with a history of cervical instability and two separate prior cervical fusion surgery with subla...

A study has been presented on the effects of intrinsic mechanical parameters, such as surface stress, surface elastic modulus, surface porosity, permeability and grain size on the corrosion failure of nanocomposite coatings. A set of mechano-electrochemical equations was developed by combining the popular Butler-Volmer and Duhem expressions to analyze the direct influence of mechanical paramete...

the idea of smart corrosion inhibition is basis on either inhibitor consumption where it is needed or reducing harmful matrix interaction with it. in addition, applying corrosion inhibitor in a coating causes many problems such as loss of inhibition capability, coating degradation, or both. a useful technique to overcome this problem is applying of inert host systems of nanometer dimensions as ...