The bronze patina is aesthetically pleasing and enhances the corrosion resistance of metallic object. This product layer can develop naturally, through aging or artificially. However, artificial methods require substances that are hazardous to human health environment. In this study, a sustainable approach development, based on anodic polarization 85.5Cu-4.2Pb-4.5Sn-5.7Zn copper alloy immersed ...

in the present study, a new gas diffusion electrode (gde) (based on pt/nafion membrane) is fabricated. the electrochemical results show that the new gde has the highest electrochemical activity toward the oxygen reduction reaction (orr) among the three electrodes. the sem and xrd findings show that a platinum layer can be attached to nafion membrane closely and firmly with a strong peak corresp...

in this study, the effects of forming method (extrusion) and environmental factors (solution ph and temperature) on the corrosion performance of az91 magnesium alloys were investigated using potentiodynamic polarization, electrochemical impedance spectroscopy (eis), scanning electron microscopy (sem) and salt spray techniques. the polarization test results of the specimens showed that simple sh...

An attempt has been made to investigate the effect of SiO2 nanoparticles on the conductivity of polypyrrole conducting polymeric films prepared by an electrochemical method. The obtained nanocomposites were characterized by FTIR, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM). The results indicate that the conductivity of the nanoco...

We report on the aptadetection of chloramphenicol (CAP) using electrochemical impedance spectroscopy. The detection principle is based on the changes of the interfacial properties of the electrode after the interaction of the ssDNA aptamers with the target molecules. The electrode surface is partially blocked due to the formation of the aptamer-CAP complex, resulting in an increase of the inter...

Corrosion resistance of pure titanium (Grade 2) and Ti−Pd alloy (Grade 7) was studied using the electrochemical techniques of potentiodynamic measurements and electrochemical impedance spectroscopy (EIS). Measurements were performed at the temperature of 36.6 °C in two solutions: PBS solution with pH of 7.4 simulating conditions of healthy human body, and PBS solution with pH of 5.2 and with th...

in this study, the corrosion resistance of a bituminous coating reinforced with different ratios ofnanoclay pigment was studied. to make nanocomposite coatings, 2, 3, and 4 wt.% of clay (cloisitena+) were incorporated into water emulsified bitumen. the coatings were applied to steel 37. opticalmicroscopy and x-ray diffraction (xrd) were used to characterize the nanocomposite structure. inorder ...

An approximate formula for the frequency of oscillations is theoretically derived for skeleton models for electrochemical systems exhibiting negative differential resistance (NDR) under conditions close to supercritical Hopf bifurcation points. The theoretically predicted omega infinity (k/R)1/2 relationship (where R is the series resistance of the cell and k is the rate constant of the charge ...

in this study, plasma electrolytic oxidation of 2024-t3 aluminum alloy was investigated. the electrolyte used in this investigation was an alkaline solution containing additives of silicate, phosphate, potassium hydroxide and glycerin. a conventional dc power source with a low applied voltage was employed. corrosion resistance of the oxide layer was investigated by means of tafel plots and elec...