This paper provides a general theoretical description of a weakly bound atomic system (a negative ion) interacting simultaneously with two (generally strong) fields, a static electric field and a monochromatic laser field having an arbitrary elliptical polarization. The zerorange δ-potential is used to model the interaction of a bound electron in a negative ion as well as the interaction of a d...

All-electron static and time-dependent DFT electronic calculations, with complete geometrical optimization, are performed on tubular molecules up to C(210)H(20) that are finite sections of the (5,5) metallic single wall carbon nanotube with hydrogen termination at the open ends. We find pronounced C-C bond reconstruction at the tube ends; this initiates bond alternation that propagates into the...

The separation of slow nuclear and fast electronic polarization in problems related to electron mobility in polarizable media was considered by Pekar 70 years ago. Within dielectric continuum models, this separation leads to the Pekar factor in the free energy of solvation by the nuclear degrees of freedom. The main qualitative prediction of Pekar's perspective is a significant, by about a fact...