Graphene oxide potentially has multiple applications. The chemistry of graphene oxide and its response to external stimuli such as temperature and light are not well understood and only approximately controlled. This understanding is crucial to enable future applications of this material. Here, a combined experimental and density functional theory study shows that multilayer graphene oxide prod...

Graphene oxide is one of the most studied nanomaterials owing to its huge application potential in many fields, including biomedicine, sensing, drug delivery, optical and optoelectronic technologies. However, a detailed description of the chemical composition and the extent of oxidation in graphene oxide remains a key challenge affecting its applicability and further development of new applicat...

The chapter gives an overview of the most important synthetic methods to produce graphene oxide via wet chemistry. Brodie-Staudenmaier-Hummers and free-water based approaches are reported and where it is considered the influence of synthesis on the graphene oxide structure. Physical chemical and morphological characterisations are described in the second part of the chapter. In the last section...

We report directly grown strongly adherent graphene on Co3O4(111) by carbon molecular beam epitaxy (C MBE) at 850 K and density functional theory (DFT) findings that the first graphene layer is reconstructed to fit the Co3O4 surface, while subsequent layers retain normal graphene structure. This adherence to the Co3O4 structure results from partial bonding of half the carbons to top oxygens of ...

Metal oxide nanoparticles supported on graphene exhibit high catalytic activity for oxidation, reduction and coupling reactions. Here we show that pyrolysis at 900 °C under inert atmosphere of copper(II) nitrate embedded in chitosan films affords 1.1.1 facet-oriented copper nanoplatelets supported on few-layered graphene. Oriented (1.1.1) copper nanoplatelets on graphene undergo spontaneous oxi...

We report the fabrication of flexible conductive graphene paper through a direct and gentle annealing process of graphene oxide paper. Thermal treatments at 700 oC under argon or hydrogen atmosphere directly applied to parent graphene oxide paper lead to a significant removal of disruptive oxygen-containing functional groups, and to a considerable recovery of the sp network structure. Detailed ...

The chapter gives an overview of the most important synthetic methods to produce graphene oxide via wet chemistry. Brodie-Staudenmaier-Hummers and free-water based approaches are reported and where it is considered the influence of synthesis on the graphene oxide structure. Physical chemical and morphological characterisations are described in the second part of the chapter. In the last section...

In this work, zinc ferrite magnetic and zinc ferrite-graphene oxide nanocomposite were synthesized through a facile hydrothermal method and dye removal capability as an adsorbent were studied. Fourier transform infrared spectroscopy FT-IR, X-ray diffraction XRD and scanning electron microscopy SEM were used to characterize the synthesized nanocomposite. The UV-Vis results showed that the additi...

This letter demonstrates that a novel, highly efficient enzyme electrode can be directly obtained using covalent attachment between carboxyl acid groups of graphene oxide sheets and amines of glucose oxidase. The resulting biosensor exhibits a broad linear range up to 28 mM x mm(-2) glucose with a sensitivity of 8.045 mA x cm(-2) x M(-1). The glucose oxidase-immobilized graphene oxide electrode...

Due to their unique structure, the optical and mechanical properties graphene and its derivatives (e.g. graphene oxide, reduced graphene oxide) have captured the attention of a constantly increasing number of scientists with regards to biomolecule sensing. This mini review focuses on one specific type of sensor, that consisting of graphene and polyelectrolytes. Polyelectrolyte-graphene nanocomp...