Mixtures of ideal polymers with hard spheres whose diameters are smaller than the radius of gyration of the polymer, exhibit extensive immiscibility. The interfacial tension between demixed phases of these mixtures is estimated, as is the barrier to nucleation. The barrier is found to scale linearly with the radius of the polymer, causing it to become large for large polymers. Thus for large po...

Light is able to remotely move matter. Among various driving forces, laser-induced metal sphere migration in glass has been reported. The temperature on the laser-illuminated side of the sphere was higher than that on the non-illuminated side. This temperature gradient caused non-uniformity in the interfacial tension between the glass and the melted metal as the tension decreased with increasin...

Gallium and mercury are employed as liquid phases in a nanoporous carbonbased energy absorption system. Owing to the large surface tensions, the nanopore surface is non-wettable. Pressure-induced infiltration is observed and defiltration is difficult. The energy absorption efficiency is much higher than that of previously investigated nanoporous silica-based systems. The nominal solid–liquid in...

We present an experimental study on the adsorption behaviour of Intan-100, a nonionic surfactant, at the bitumen/water interface when the density difference between the two phases is increased by diluting the crude oil with 10% Xylene by weight or using heavy water (Deuterium Oxide) as the aqueous phase. Their equilibrium interfacial tension, surface excess and critical micelle concentration of...

Glas and Bahr (1) have proposed a method for the determination of the water content of subcellular particles which can be schematically described as follows: A suspension of particles in 0.44 M sucrose is layered in a centrifuge tube over a silicone oil denser than the sucrose solution but less dense than the particles. The particles are sedimented through the silicone oil by high speed centrif...

Wettability alteration has been a sophisticated issue for scientists and reservoir engineers since early 20th century; thus, many investigations have been carried out to determine wettability and enhance it to ideal conditions, which leads to improvement in oil recovery. Dilute surfactant flooding has been approved as one of the noteworthy methods in chemical flooding. Several petroleum reservo...

A major portion of BaSO4 is used as drilling fluid additives in the presence of some biopolymers such as starch and PAC (Polyanionic Cellulose) as filtration control and viscosifier. BaSO4 nanoparticle was synthesized in the presence of these applicable polymers with precipitation method by using BaS produced from carbothermal method and Na2SO4. Synthesized nanoparticles size and morphology wer...

We describe an experimental technique for the production of highly monodisperse emulsions (with minimum achievable polydispersities < 3%). The phase to be dispersed is introduced into a coowing, surfactant laden continuous phase via a tapered capillary. Drops detach from the capillary when the streamwise forces exceed the force due to interfacial tension. Drop size is a function of the capillar...

Drop dynamics plays a central role in defining the interfacial morphology in two-phase complex fluids such as emulsions and polymer blends. In such materials, the components are often microstructured complex fluids themselves. To model and simulate drop behavior in such systems, one has to deal with the dual complexity of non-Newtonian rheology and evolving interfaces. Recently, we developed a ...

Vapor-liquid interfacial properties of square-well associating fluids are studied via transition-matrix Monte Carlo simulation. Results for one-site and two-site association models are presented. Coexistence properties, surface tension, cluster distribution, density profile, and orientation profile are presented. Molecular association affects the interfacial properties and cluster fractions mor...