New solid strong bases were fabricated at room temperature by grafting lithium-containing molecular precursors onto β-cyclodextrin. The solid bases show strong basicity with a molecular-level dispersion of lithium sites, which are highly active in transesterification reactions and impossible to realize through the traditional high-temperature method.

A singular operator with Cauchy kernel on the subspaces of weight Lebesgue space is considered. A sufficient condition for a bounded action of this operator from a subspace to another subspace of weight Lebesgue space of functions is found. These conditions are not identical withMuckenhoupt conditions. Moreover, the completeness, minimality, and basicity of sines and cosines systems are conside...

A redox strategy was designed to generate strong basicity on mesoporous silica by using the redox interaction of a precursor with methanol vapor. The formation of strongly basic sites was realized at 400 °C, which breaks the tradition of thermally induced decomposition that usually requires much higher temperatures (>600 °C).

The phisico-chemical properties of bio-and drug molecules greatly influence their interactions in the body and strongly effect the mechanism of drug action. Among these properties, macroscopic and site-specific protonation constants are of crucial importance. Latter one is the tool to calculate the relative concentration of the various microspecies in the compartments of the body at different p...

Extensive exploration of the conformational space of neutral, protonated and deprotonated histidine has been conducted at the G4MP2 level. Theoretical protonation and deprotonation thermochemistry as well as heats of formation of gaseous histidine and its ionized forms have been calculated at the G4 level considering either the most stable conformers or an equilibrium population of conformers a...

Cu/ZnO catalysts were synthesized on Al2O3-ZrO2 support via impregnation method with addition of manganese and niobium promoters. Samples calcined at 181, 350 518 ºC. Different characterization techniques such as H2-TPR CO2-TPD used to study the catalytic reduction behavior basicity, respectively. studies shows that all occurred range temperature between 237 ºC 265 The profiles showed calcinati...