a thermophilic anaerobic contact reactor for the treatment of potato-processing wastewaterswas designed as a continuous-flow, completely-mixed homogeneous system. the reactor was operated at ten different organic loading rates ranging from 0.84 g cod/l·d to 7.00 g cod/l·d for a duration of approximately 250 days. the fundamental way to maintain optimum operating conditions of anaerobic digestio...

The behavior of an atom in a nonuniform magnetic field is analyzed, as well as the motion of a classical magnetic dipole (a spinning charged ball) and a rotating charged ring. For the atom it is shown that, while the magnetic field does no work on the electron-orbital contribution to the magnetic moment (the source of translational kinetic energy being the internal energy of the atom), whether ...

The olefins polymerization process in a slurry reactor is discussed. The reaction rate dynamics was analyzed and the contributions of feed flow, gas-liquid mass transfer, polymerization reaction, and catalyst deactivation were estimated. The propylene solubility in a solvent mixture “heptane” was calculated using Soave-Redlich-Kwong equation of state. These data were then approximated by Henry-...

This paper reports the synthesis of a 3-hydroxypropyl analog of HMPA. This ligand will be coordinated to SmI2, and kinetic studies are performed. This is worthy of study because the protonation step of the reduction mechanism, which typically occurs intermolecularly in SmI2-mediated reductions of carbonyls, will occur intramolecularly; thus, the potential exists for rate enhancement. The comple...

Herein a quenched-flow kinetic technique was applied to calculate the rate constants of 1-hexene and 1-octene oligomerization catalyzed by the Cp2ZrCl2 and Cp2HfCl2/MAO catalyst systems, and subsequently a mechanism for the higher α-olefin oligomerization reaction was proposed. The oligomerization results showed that Zr-based catalyst in the oligomerization of 1-octene had the highest activity ...

A differential scanning calorimetry study on the thermal denaturation of concanavalin A at pH 5.2 where it exists in the dimeric form was carried out. The calorimetric transitions were observed to be irreversible and the transition temperature of the protein increased with increasing scan rate, indicating that the thermal denaturation process is under kinetic control. The thermal unfolding, and...

The human oncogene c-myc is regulated by G-quadruplex formation within the nuclease hypersensitive element (NHE III(I)) in the c-myc promoter, making the quadruplex a strong anti-cancer target. With respect to this, the competing equilibrium between intramolecular quadruplex folding and bimolecular duplex formation is poorly understood and very few techniques have addressed this problem. We pre...

Yeast cytosine deaminase (yCD), a zinc metalloenzyme, catalyzes the hydrolytic deamination of cytosine to uracil. The enzyme is of great biomedical interest because it also catalyzes the deamination of the prodrug 5-fluorocytosine (5FC) to form the anticancer drug 5-fluorouracil (5FU). yCD/5FC is one of the most widely used enzyme/prodrug combinations for gene-directed enzyme prodrug therapy fo...